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Equal abundance of summertime natural and wintertime anthropogenic Arctic organic aerosols

Moschos, Vaios; Dzepina, Katja; Bhattu, Deepika; Lamkaddam, Houssni; Casotto, Roberto; Daellenbach, Kaspar R.; Canonaco, Francesco; Rai, Pragati; Aas, Wenche; Becagli, Silvia; Calzolai, Giulia; Eleftheriadis, Konstantinos; Moffett, Claire E.; Schnelle-Kreis, Jürgen; Seviri, Mirko; Sharma, Sangeeta; Skov, Henrik; Vestenius, Mika; Zhang, Wendy; Hakola, Hannele; Hellén, Heidi; Huang, Lin; Jaffrezo, Jean-Luc; Massling, Andreas; Nøjgaard, Jacob Klenø; Petäjä, Tuukka; Popovicheva, Olga; Sheesley, Rebecca J.; Traversi, Rita; Yttri, Karl Espen; Schmale, Julia; Prévôt, André S. H.; Baltensperger, Urs; Haddad, Imad El

Aerosols play an important yet uncertain role in modulating the radiation balance of the sensitive Arctic atmosphere. Organic aerosol is one of the most abundant, yet least understood, fractions of the Arctic aerosol mass. Here we use data from eight observatories that represent the entire Arctic to reveal the annual cycles in anthropogenic and biogenic sources of organic aerosol. We show that during winter, the organic aerosol in the Arctic is dominated by anthropogenic emissions, mainly from Eurasia, which consist of both direct combustion emissions and long-range transported, aged pollution. In summer, the decreasing anthropogenic pollution is replaced by natural emissions. These include marine secondary, biogenic secondary and primary biological emissions, which have the potential to be important to Arctic climate by modifying the cloud condensation nuclei properties and acting as ice-nucleating particles. Their source strength or atmospheric processing is sensitive to nutrient availability, solar radiation, temperature and snow cover. Our results provide a comprehensive understanding of the current pan-Arctic organic aerosol, which can be used to support modelling efforts that aim to quantify the climate impacts of emissions in this sensitive region.

2022

Ammonia emission estimates using CrIS satellite observations over Europe

Ding, Jieying; A, Ronald van der; Eskes, Henk; Dammers, Enrico; Shephard, Mark; Kruit, Roy Wichink; Guevara, Marc; Tarrasón, Leonor

Over the past century, ammonia (NH3) emissions have increased with the growth of livestock and fertilizer usage. The abundant NH3 emissions lead to secondary fine particulate matter (PM2.5) pollution, climate change, and a reduction in biodiversity, and they affect human health. Up-to-date and spatially and temporally resolved information on NH3 emissions is essential to better quantify their impact. In this study we applied the existing Daily Emissions Constrained by Satellite Observations (DECSO) algorithm to NH3 observations from the Cross-track Infrared Sounder (CrIS) to estimate NH3 emissions. Because NH3 in the atmosphere is influenced by nitrogen oxides (NOx), we implemented DECSO to estimate NOx and NH3 emissions simultaneously. The emissions are derived over Europe for 2020 on a spatial resolution of 0.2°×0.2° using daily observations from both CrIS and the TROPOspheric Monitoring Instrument (TROPOMI; on the Sentinel-5 Precursor (S5P) satellite). Due to the limited number of daily satellite observations of NH3, monthly emissions of NH3 are reported. The total NH3 emissions derived from observations are about 8 Tg yr−1, with a precision of about 5 %–17 % per grid cell per year over the European domain (35–55° N, 10° W–30° E). The comparison of the satellite-derived NH3 emissions from DECSO with independent bottom-up inventories and in situ observations indicates a consistency in terms of magnitude on the country totals, with the results also being comparable regarding the temporal and spatial distributions. The validation of DECSO over Europe implies that we can use DECSO to quickly derive fairly accurate monthly emissions of NH3 over regions with limited local information on NH3 emissions.

2024

Observed recent change in climate and potential for decay of Norwegian wood structures

Grøntoft, Terje

The wood rot decay of structures and buildings in Norway represents high costs. This paper reports the observed trends for the potential rot decay of Norwegian wood structures in the cities of Oslo and Bergen over the recent 55 years, calculated as the “wood rot climate index” developed by Scheffer, and compares the reports with previous reported values based on climate change modelling. The observed change in the wood rot climate index was close to the modelling result. Bergen is exposed directly to the westerly Atlantic winds and has among the highest rain amounts in Norway, whereas Oslo is shielded by the Scandinavian mountain chain and has much less rain. The change in the wood rot climate index since 1961 was about 20% in both cities, but the trend in the index (climate index change per year) was about 80% stronger in Bergen. The absolute index changes were largest in the summer; then spring (50 to 60% of the summer increase); and small, zero, or even negative (autumn in Oslo) in the remaining seasons. The relative changes were higher in the spring than summer and very high in Bergen in the winter from a low value. The change to positive index values in the spring and winter indicates temperature and humidity conditions favoring the growth of wood rot and, thus, extended the rot duration through the year. The expected increase in the future wood rot decay potential in Norway shows the need for increased focus on adaption measures to reduce the related damages and costs.

2019

Soil pollution at a major West African E-waste recycling site: Contamination pathways and implications for potential mitigation strategies

Möckel, Claudia; Breivik, Knut; Nøst, Therese Haugdahl; Sankoh, Alhaji; Jones, Kevin C.; Sweetman, Andrew

Organic contaminants (polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), and chlorinated paraffins (CPs)) and heavy metals and metalloids (Ag, Cd, Co, Cr, Cu, Hg, Ni, Pb, Sb, Zn) were analysed in surface soil samples from the Agbogbloshie e-waste processing and dumping site in Accra (Ghana). In order to identify which of the pollutants are likely to be linked specifically to handling of e-waste, samples were also collected from the Kingtom general waste site in Freetown (Sierra Leone). The results were compared using principal component analyses (PCA). PBDE congeners found in technical octa-BDE mixtures, highly chlorinated PCBs and several heavy metals (Cu, Pb, Ni, Cd, Ag and Hg) showed elevated concentrations in the soils that are likely due to contamination by e-waste. PCAs associated those compounds with pyrogenic PAHs, suggesting that burning of e-waste, a common practice to isolate valuable metals, may cause this contamination. Moreover, other contamination pathways, especially incorporation of waste fragments into the soil, also appeared to play an important role in determining concentrations of some of the pollutants in the soil. Concentrations of several of these compounds were extremely high (especially PBDEs, heavy metals and SCCPs) and in some cases exceeded action guideline levels for soil. This indicates that exposure to these contaminants via the soil alone is potentially harmful to the recyclers and their families living on waste sites. Many organic contaminants and other exposure pathways such as inhalation are not yet included in such guidelines but may also be significant, given that deposition from the air following waste burning was identified as a major pollutant source.

2020

Environmental impacts of a chemical looping combustion power plant

Thorne, Rebecca Jayne; Bouman, Evert; Sundseth, Kyrre; Sanchez, Maria Asuncion Aranda; Czakiert, Tomasz; Pacyna, Jozef M; Pacyna, Elisabeth G; Krauz, Mariusz; Celińska, Agnieszka

Chemical Looping Combustion (CLC) is a promising CO2 capture option since it inherently separates CO2 from other flue components, theoretically with low energy penalty. Here, a Life Cycle Assessment model was developed of a theoretical hybrid CLC (HCLC) power plant facility utilising experimental data for CuO based oxygen carrier (OC) production and oxygen capacity. Power plant models with and without post-combustion CO2 capture, recognised as the most mature capture technology, acted as environmental performance targets. Results show that when OC is produced at lab-scale without optimisation, almost all (>99.9%) lifecycle impacts per kWh electricity from an HCLC plant derive from the specific OC material used, giving a total of ˜700 kg CO2eq/kWh. This is related to high electrical input required for OC processing, as well as high OC losses during production and from plant waste. Only when processing parameters are optimised and OC recycling from plant waste is implemented - reducing fresh OC needs – is the environmental impact lower than the conventional technologies studied (e.g. 0.2 kg CO2 eq/kWh vs. ˜0.3-1 kg CO2 eq/kWh, respectively). Further research should thus focus on identifying OCs that do not require energy intensive processing and can endure repeated cycles, allowing for recycling.

2019

An In Vitro Dosimetry Tool for the Numerical Transport Modeling of Engineered Nanomaterials Powered by the Enalos RiskGONE Cloud Platform

Cheimarios, Nikolaos; Pem, Barbara; Tsoumanis, Andreas; Ilic, Krunoslav; Vrček, Ivana Vinković; Melagraki, Georgia; Bitounis, Dimitrios; Isigonis, Panagiotis; Dusinska, Maria; Lynch, Iseult; Demokritou, Philip; Afantitis, Antreas

A freely available “in vitro dosimetry” web application is presented enabling users to predict the concentration of nanomaterials reaching the cell surface, and therefore available for attachment and internalization, from initial dispersion concentrations. The web application is based on the distorted grid (DG) model for the dispersion of engineered nanoparticles (NPs) in culture medium used for in vitro cellular experiments, in accordance with previously published protocols for cellular dosimetry determination. A series of in vitro experiments for six different NPs, with Ag and Au cores, are performed to demonstrate the convenience of the web application for calculation of exposure concentrations of NPs. Our results show that the exposure concentrations at the cell surface can be more than 30 times higher compared to the nominal or dispersed concentrations, depending on the NPs’ properties and their behavior in the cell culture medium. Therefore, the importance of calculating the exposure concentration at the bottom of the cell culture wells used for in vitro arrays, i.e., the particle concentration at the cell surface, is clearly presented, and the tool introduced here allows users easy access to such calculations. Widespread application of this web tool will increase the reliability of subsequent toxicity data, allowing improved correlation of the real exposure concentration with the observed toxicity, enabling the hazard potentials of different NPs to be compared on a more robust basis.

2022

Investigating lightweight and interpretable machine learning models for efficient and explainable stress detection

Ghose, Debasish; Chatterjee, Ayan; Balapuwaduge, Indika A.M.; Lin, Yuan; Dash, Soumya P.

Stress is a common human reaction to demanding circumstances, and prolonged and excessive stress can have detrimental effects on both mental and physical health. Heart rate variability (HRV) is widely used as a measure of stress due to its ability to capture variations in the time intervals between heartbeats. However, achieving high accuracy in stress detection through machine learning (ML), using a reduced set of statistical features extracted from HRV, remains a significant challenge. In this study, we aim to address these challenges by proposing lightweight ML models that can effectively detect stress using minimal HRV features and are computationally efficient enough for IoT deployment. We have developed ML models incorporating efficient feature selection techniques and hyper-parameter tuning. The publicly available SWELL-KW dataset has been utilized for evaluating the performance of our models. Our results demonstrate that lightweight models such as k-NN and Decision Tree can achieve competitive accuracy while ensuring lower computational demands, making them ideal for real-time applications. Promisingly, among the developed models, the k-nearest neighbors (k-NN) algorithm has emerged as the best-performing model, achieving an accuracy score of 99.3% using only three selected features. To confirm real-world deployability, we benchmarked the best model on an 8 GB NVIDIA Jetson Orin Nano edge device, where it retained 99.26% accuracy and completed training in 31 s. Furthermore, our study has incorporated local interpretable model-agnostic explanations to provide comprehensive insights into the predictions made by the k-NN-based architecture.

2025

Clean air policies are key for successfully mitigating Arctic warming

Salzen, Knut von; Whaley, Cynthia; Anenberg, Susan C.; Dingenen, Rita Van; Klimont, Zbigniew; Flanner, Mark G.; Mahmood, Rashed; Arnold, Stephen R.; Beagley, Stephen; Chien, Rong-You; Christensen, Jesper H.; Eckhardt, Sabine; Ekman, Annica M. L.; Evangeliou, Nikolaos; Faluvegi, Greg; Fu, Joshua S.; Gauss, Michael; Gong, Wanmin; Hjorth, Jens; Im, Ulas; Krishnan, Srinath; Kupiainen, Kaarle; Kuhn, Thomas; Langner, Joakim; Law, Kathy S.; Marelle, Louis; Oliviè, Dirk Jan Leo; Onishi, Tatsuo; Oshima, Naga; Paunu, Ville-Veikko; Peng, Yiran; Plummer, David; Pozzoli, Luca; Rao-Skirbekk, Shilpa; Raut, Jean-Christophe; Sand, Maria; Schmale, Julia; Sigmond, Michael; Thomas, Manu Anna; Tsigaridis, Kostas; Tsyro, Svetlana; Turnock, Steven T.; Wang, Minqi; Winter, Barbara

A tighter integration of modeling frameworks for climate and air quality is urgently needed to assess the impacts of clean air policies on future Arctic and global climate. We combined a new model emulator and comprehensive emissions scenarios for air pollutants and greenhouse gases to assess climate and human health co-benefits of emissions reductions. Fossil fuel use is projected to rapidly decline in an increasingly sustainable world, resulting in far-reaching air quality benefits. Despite human health benefits, reductions in sulfur emissions in a more sustainable world could enhance Arctic warming by 0.8 °C in 2050 relative to the 1995–2014, thereby offsetting climate benefits of greenhouse gas reductions. Targeted and technically feasible emissions reduction opportunities exist for achieving simultaneous climate and human health co-benefits. It would be particularly beneficial to unlock a newly identified mitigation potential for carbon particulate matter, yielding Arctic climate benefits equivalent to those from carbon dioxide reductions by 2050.

2022

Comparison of young male mice of two different strains (C57BL/6J and the hybrid B6129SF1/J) in selected behavior tests. A small scale study

Hansen, Kristine Eraker Aasland; Hudecova, Alexandra Misci; Haugen, Fred; Skjerve, Eystein; Ropstad, Erik; Zimmer, Karin Elisabeth

BACKGROUND
All mouse strains are different, before choosing a strain for a large study, a small scale study should be done. In this study, we compared young males of two mouse strains, C57BL/6J and the hybrid B6129SF1/J, and gained knowledge on their performance in three different behavioral tests; open field (OF) test, Barnes maze (BM) test and a restraint stress test.

RESULTS
We found that the young males of the C57BL/6J strain spent more time moving in the OF. In the BM, the hybrid covered less ground before reaching the goal box during the first three sessions, than the C57BL/6J. The hybrid left more fecal pellets than C57BL/6J both in OF and BM. During the stress test, the C57BL/6J had a lower corticosterone response than the hybrid.

CONCLUSIONS
Our findings indicate that the C57BL/6J has a presumably higher locomotor activity and/or explorative behavior than the hybrid, while the hybrid appeared more sensitive to stress.

2022

Siberian Arctic black carbon: gas flaring and wildfire impact

Popovicheva, Olga; Evangeliou, Nikolaos; Kobelev, Vasily O.; Chichaeva, M. A.; Eleftheriadis, Konstantinos; Gregorič, Asta; Kasimov, Nikolay

As explained in the latest Arctic Monitoring and Assessment Programme (AMAP) report released in early 2021, the Arctic has warmed 3 times more quickly than the planet as a whole, as well as faster than previously thought. The Siberian Arctic is of great interest mainly because observations are sparse or largely lacking. A research aerosol station has been developed on Bely Island (Kara Sea) in western Siberia. Measurements of equivalent black carbon (EBC) concentrations were carried out at the “Island Bely” station continuously from August 2019 to November 2020. The source origin of the measured EBC and the main contributing sources were assessed using atmospheric transport modeling coupled with the most updated emission inventories for anthropogenic and biomass burning sources of BC.

The obtained climatology for BC during the period of measurements showed an apparent seasonal variation with the highest concentrations between December and April (60 ± 92 ng m−3) and the lowest between June and September (18 ± 72 ng m−3), typical of the Arctic haze seasonality reported elsewhere. When air masses arrived at the station through the biggest oil and gas extraction regions of Kazakhstan, Volga-Ural, Komi, Nenets and western Siberia, BC contribution from gas flaring dominated over domestic, industrial and traffic sectors, ranging from 47 % to 68 %, with a maximum contribution in January. When air was transported from Europe during the cold season, emissions from transportation were more important. Accordingly, shipping emissions increased due to the touristic cruise activities and the ice retreat in summertime. Biomass burning (BB) played the biggest role between April and October, contributing 81 % at maximum in July. Long-range transport of BB aerosols appeared to induce large variability to the absorption Ångström exponent (AAE) with values > 1.0 (excluding outliers). As regards the continental contribution to surface BC at the Island Bely station, Russian emissions dominated during the whole year, while European and Asian ones contributed up to 20 % in the cold period. Quantification of several pollution episodes showed an increasing trend in surface concentrations and frequency during the cold period as the station is directly in the Siberian gateway of the highest anthropogenic pollution sources to the Russian Arctic.

2022

Relationship between cloud condensation nuclei (CCN) concentration and aerosol optical depth in the Arctic region

Ahn, Seo H.; Yoon, Young-Jun; Choi, Taejin; Lee, Jiyi; Kim, Yong Pyo; Lee, Bangyoung Young; Ritter, Christoph; Aas, Wenche; Krejčí, Radovan; Ström, Johan; Tunved, Peter; Jung, Chang-hoon

2021

Inferring surface energy fluxes using drone data assimilation in large eddy simulations

Pirk, Norbert; Aalstad, Kristoffer; Westermann, Sebastian; Vatne, Astrid; Hove, Alouette van; Tallaksen, Lena Merete; Cassiani, Massimo; Katul, Gabriel G.

Spatially representative estimates of surface energy exchange from field measurements are required for improving and validating Earth system models and satellite remote sensing algorithms. The scarcity of flux measurements can limit understanding of ecohydrological responses to climate warming, especially in remote regions with limited infrastructure. Direct field measurements often apply the eddy covariance method on stationary towers, but recently, drone-based measurements of temperature, humidity, and wind speed have been suggested as a viable alternative to quantify the turbulent fluxes of sensible (H) and latent heat (LE). A data assimilation framework to infer uncertainty-aware surface flux estimates from sparse and noisy drone-based observations is developed and tested using a turbulence-resolving large eddy simulation (LES) as a forward model to connect surface fluxes to drone observations. The proposed framework explicitly represents the sequential collection of drone data, accounts for sensor noise, includes uncertainty in boundary and initial conditions, and jointly estimates the posterior distribution of a multivariate parameter space. Assuming typical flight times and observational errors of light-weight, multi-rotor drone systems, we first evaluate the information gain and performance of different ensemble-based data assimilation schemes in experiments with synthetically generated observations. It is shown that an iterative ensemble smoother outperforms both the non-iterative ensemble smoother and the particle batch smoother in the given problem, yielding well-calibrated posterior uncertainty with continuous ranked probability scores of 12 W m−2 for both H and LE, with standard deviations of 37 W m−2 (H) and 46 W m−2 (LE) for a 12 min vertical step profile by a single drone. Increasing flight times, using observations from multiple drones, and further narrowing the prior distributions of the initial conditions are viable for reducing the posterior spread. Sampling strategies prioritizing space–time exploration without temporal averaging, instead of hovering at fixed locations while averaging, enhance the non-linearities in the forward model and can lead to biased flux results with ensemble-based assimilation schemes. In a set of 18 real-world field experiments at two wetland sites in Norway, drone data assimilation estimates agree with independent eddy covariance estimates, with root mean square error values of 37 W m−2 (H), 52 W m−2 (LE), and 58 W m−2 (H+LE) and correlation coefficients of 0.90 (H), 0.40 (LE), and 0.83 (H+LE). While this comparison uses the simplifying assumptions of flux homogeneity, stationarity, and flat terrain, it is emphasized that the drone data assimilation framework is not confined to these assumptions and can thus readily be extended to more complex cases and other scalar fluxes, such as for trace gases in future studies.

2022

Year-Round In Situ Measurements of Arctic Low-Level Clouds: Microphysical Properties and Their Relationships With Aerosols

Koike, Makoto; Ukita, Jinro; Ström, Johan; Tunved, Peter; Shiobara, Masataka; Vitale, Vito; Lupi, Angelo; Baumgardner, D.; Ritter, Christoph; Hermansen, Ove; Yamada, K.; Pedersen, Christina Alsvik

Two years of continuous in situ measurements of Arctic low‐level clouds have been made at the Mount Zeppelin Observatory (78°56′N, 11°53′E), in Ny‐Ålesund, Spitsbergen. The monthly median value of the cloud particle number concentration (Nc) showed a clear seasonal variation: Its maximum appeared in May–July (65 ± 8 cm−3), and it remained low between October and March (8 ± 7 cm−3). At temperatures warmer than 0 °C, a clear correlation was found between the hourly Nc values and the number concentrations of aerosols with dry diameters larger than 70 nm (N70), which are proxies for cloud condensation nuclei (CCN). When clouds were detected at temperatures colder than 0 °C, some of the data followed the summertime Nc to N70 relationship, while other data showed systematically lower Nc values. The lidar‐derived depolarization ratios suggested that the former (CCN‐controlled) and latter (CCN‐uncontrolled) data generally corresponded to clouds consisting of supercooled water droplets and those containing ice particles, respectively. The CCN‐controlled data persistently appeared throughout the year at Zeppelin. The aerosol‐cloud interaction index (ACI = dlnNc/(3dlnN70)) for the CCN‐controlled data showed high sensitivities to aerosols both in the summer (clean air) and winter–spring (Arctic haze) seasons (0.22 ± 0.03 and 0.25 ± 0.02, respectively). The air parcel model calculations generally reproduced these values. The threshold diameters of aerosol activation (Dact), which account for the Nc of the CCN‐controlled data, were as low as 30–50 nm when N70 was less than 30 cm−3, suggesting that new particle formation can affect Arctic cloud microphysics.

2019

Comprehensive characterization of European house dust contaminants: Concentrations and profiles, geographical variability, and implications for chemical regulation and health risk

Haglund, Peter; Alygizakis, Nikiforos A.; Covaci, Adrian; Melymuk, Lisa; Bohlin-Nizzetto, Pernilla; Rostkowski, Pawel; Albinet, Alexandre; Alirai, Sylvana; Aurich, Dagny; Bieber, Stefan; Ballesteros-Gómez, Ana; Brennan, Amanda; Budzinski, Hélène; Castro, Gabriela; Ouden, Fatima den; Dévier, Marie-Hélène; Dulio, Valeria; Feng, Yong-Lai; Gabriel, Marta; Gallampois, Christine; Garcia-Vara, Manuel; Giovanoulis, Georgios; Harrad, Stuart; Jacobs, Griet; Jobst, Karl J.; Kaserzon, Sarit; Kumirska, Jolanta; Lestremau, Francois; Lambropoulou, Dimitra; Letzel, Thomas; Alda, Miren López de; Nipen, Maja; Oswald, Peter; Poma, Giulia; Přibylová, Petra; Price, Elliott J.; Raffy, Gaëlle; Schulze, Bastian; Schymanski, Emma L.; Senk, Petr; Wei, Si; Slobodnik, Jaroslav; Andújar, Begoña Talavera; Täubel, Martin; Thomaidis, Nikolaos S.; Wang, Thanh; Wang, Xianyu

2024

Impacts of UV irradiance and medium-energy electron precipitation on the North Atlantic oscillation during the 11-year solar cycle

Guttu, Sigmund; Orsolini, Yvan; Stordal, Frode; Otterå, Odd Helge; Omrani, Nour-Eddine; Tartaglione, Nazario; Verronen, Pekka T.; Rodger, Craig J.; Clilverd, Mark A.

Observational studies suggest that part of the North Atlantic Oscillation (NAO) variability may be attributed to the spectral ultra-violet (UV) irradiance variations associated to the 11-year solar cycle. The observed maximum surface pressure response in the North Atlantic occurs 2–4 years after solar maximum, and some model studies have identified that atmosphere–ocean feedbacks explain the multi-year lag. Alternatively, medium-to-high energy electron (MEE) precipitation, which peaks in the declining phase of the solar cycle, has been suggested as a potential cause of this lag. We use a coupled (ocean–atmosphere) climate prediction model and a state-of-the-art MEE forcing to explore the respective roles of irradiance and MEE precipitation on the NAO variability. Three decadal ensemble experiments were conducted over solar cycle 23 in an idealized setting. We found a weak ensemble-mean positive NAO response to the irradiance. The simulated signal-to-noise ratio remained very small, indicating the predominance of internal NAO variability. The lack of multi-annual lag in the NAO response was likely due to lagged solar signals imprinted in temperatures below the oceanic mixed-layer re-emerging equatorward of the oceanic frontal zones, which anchor ocean–atmosphere feedbacks. While there is a clear, yet weak, signature from UV irradiance in the atmosphere and upper ocean over the North Atlantic, enhanced MEE precipitation on the other hand does not lead to any systematic changes in the stratospheric circulation, despite its marked chemical signatures.

2021

Springtime nitrogen oxides and tropospheric ozone in Svalbard: results from the measurement station network

Dekhtyareva, Alena; Hermanson, Mark H.; NIkulina, Anna; Hermansen, Ove; Svendby, Tove Marit; Holmén, Kim; Graversen, Rune Grand

Svalbard is a remote and scarcely populated Arctic archipelago and is considered to be mostly influenced by long-range-transported air pollution. However, there are also local emission sources such as coal and diesel power plants, snowmobiles and ships, but their influence on the background concentrations of trace gases has not been thoroughly assessed. This study is based on data of tropospheric ozone (O3) and nitrogen oxides (NOx) collected in three main Svalbard settlements in spring 2017. In addition to these ground-based observations and radiosonde and O3 sonde soundings, ERA5 reanalysis and BrO satellite data have been applied in order to distinguish the impact of local and synoptic-scale conditions on the NOx and O3 chemistry. The measurement campaign was divided into several sub-periods based on the prevailing large-scale weather regimes. The local wind direction at the stations depended on the large-scale conditions but was modified due to complex topography. The NOx concentration showed weak correlation for the different stations and depended strongly on the wind direction and atmospheric stability. Conversely, the O3 concentration was highly correlated among the different measurement sites and was controlled by the long-range atmospheric transport to Svalbard. Lagrangian backward trajectories have been used to examine the origin and path of the air masses during the campaign.

2022

Legacy and emerging flame retardants (FRs) in the urban atmosphere of Pakistan: Diurnal variations, gas-particle partitioning and human health exposure

Syed, Jabir Hussain; Iqbal, Mehreen; Breivik, Knut; Chaudhry, Muhammad Jamshed Iqbal; Shahnawaz, Muhammad; Abbas, Zaigham; Nasir, Jawad; Rizvi, Syed Hussain Haider; Taqi, Malik Mumtaz Hussain; Li, Jun; Zhang, Gan

2020

Thymidine Kinase+/− Mammalian Cell Mutagenicity Assays for Assessment of Nanomaterials

Chen, Tao; Dusinska, Maria; Elespuru, Rosalie K.

The methods outlined here are part of a series of papers designed specifically for genotoxicity assessment of nanomaterials (NM). Common Considerations such as NM characterization, sample preparation and dose selection, relevant to all genotoxicity assays, are found in an accompanying paper. The present paper describes methods for evaluation of mutagenicity in the mammalian (mouse) thymidine kinase (Tk) gene occurring in L5178Y mouse lymphoma (ML) cells and in the designated TK gene in human lymphoblastoid TK6 cells. Mutations change the functional genotype from TK+/− to TK−/−, detectable as cells surviving on media selective for the lack of thymidine kinase (TK) function. Unlike cells with TK enzyme function, the TK−/− cells are unable to integrate the toxic selection agent, allowing these cells to survive as rare mutant colonies. The ML assay has been shown to detect a broad spectrum of genetic damage, including both small scale (point) mutations and chromosomal alterations. This assay is a widely used mammalian cell gene mutation assay for regulatory purposes and is included in the core battery of genotoxicity tests for regulatory decision-making. The TK6 assay is an assay using a human cell line derived similarly via mutagenic manipulations and optimal selection. Details are provided on the materials required, cell culture methods, selection of test chemical concentrations, cytotoxicity, treatment time, mutation expression, cloning, and data calculation and interpretation. The methods describe the microwell plate version of the assays without metabolic activation.

2022

Thermodynamic and electron paramagnetic resonance descriptors of TiO2 nanoforms interaction with plasma albumin: The interplay between energetic parameters and nanomaterial's toxicity

Gheorghe, Daniela; Precupas, Aurica; Botea-Petcu, Alina; Sandu, Romica; Teodorescu, Florina; Leonties, Anca Ruxandra; Popa, Vlad Tudor; Matei, Iulia; Ionita, Gabriela; Yamani, Naouale El; Ostermann, Melanie; Sauter, Alexander; Jensen, Keld Alstrup; Cimpan, Mihaela Roxana; Rundén-Pran, Elise; Dusinska, Maria; Tanasescu, Speranta

2025

Thermal conditions during heat waves of a mid-European metropolis under consideration of climate change, urban development scenarios and resilience measures for the mid-21st century

Trimmel, Heidelinde; Weihs, Philipp; Faroux, Stephanie; Formayer, Herbert; Hamer, Paul David; Hasel, Kristoffer; Laimighofer, Johannes; Leidinger, David; Masson, Valery; Nadeem, Imran; Oswald, Sandro M.; Revesz, Michael; Schoetter, Robert

In this study we produce two urban development scenarios estimating potential urban sprawl and optimized development concerning building construction, and we simulate their influence on air temperature, surface temperatures and human thermal comfort. We select two heat waves representative for present and future conditions of the mid 21st century and simulations are run with the Town Energy Balance Model (TEB) coupled online and offline to the Weather Research and Forecasting Model (WRF). Global and regional climate change under the RCP8.5 scenario causes an increase of daily maximum air temperature in Vienna by 7 K. The daily minimum air temperature will increase by 2–4 K. Changes caused by urban growth or densification mainly affect air temperature and human thermal comfort locally where new urbanisation takes place and does not occur significantly in the central districts. A combination of near zero-energy standards and increasing albedo of building materials on the city scale accomplishes a maximum reduction of urban canyon temperature achieved by changes in urban parameters of 0.9 K for the minima and 0.2 K for the maxima. Local scale changes of different adaptation measures show that insulation of buildings alone increases the maximum wall surface temperatures by more than 10 K or the maximum mean radiant temperature (MRT) in the canyon by 5 K. Therefore, measures to reduce MRT within the urban canyons like tree shade are needed to complement the proposed measures. This study concludes that the rising air temperatures expected by climate change puts an unprecedented heat burden on Viennese inhabitants, which cannot easily be reduced by measures concerning buildings within the city itself. Additionally, measures such as planting trees to provide shade, regional water sensitive planning and global reduction of greenhouse gas emissions in order to reduce temperature extremes are required.

2019

Emissions of Tetrafluoromethane (CF4) and Hexafluoroethane (C2F6) From East Asia: 2008 to 2019

Kim, Jooil; Thompson, Rona Louise; Park, Hyeri; Bogle, Stephanie; Mühle, Jens; Park, Mi-Kyung; Kim, Yeaseul; Harth, Christina M.; Salameh, Peter K.; Schmidt, Roland; Ottinger, Deborah; Park, Sunyoung; Weiss, Ray F.

The perfluorocarbons (PFCs), tetrafluoromethane (CF4) and hexafluoroethane (C2F6), are potent greenhouse gases with very long atmospheric lifetimes. They are emitted almost entirely from industrial sources, including the aluminum and rare earth metal smelting industries that emit them as by-products, and the semiconductor and flat panel display manufacturing industries that use them and vent unutilized amounts to the atmosphere. Despite extensive industrial efforts to quantify and curb these emissions, “top-down” PFC emission estimates derived from atmospheric measurements continue to rise and are significantly greater than reported process- and inventory-based “bottom-up” emissions. In this study, we estimate emissions of CF4 and C2F6 from East Asia, where PFC emitting industries are heavily concentrated, using a top-down approach (a Bayesian inversion) with high-frequency atmospheric measurements at Gosan (Jeju Island, South Korea) for 2008–2019. We also compile and analyze the available bottom-up CF4 and C2F6 emissions in East Asia from industrial and government reports. Our results suggest that the observed increases in global PFC emissions since 2015 are driven primarily by China's aluminum industry, with significant contributions from Japan's and Korea's semiconductor industry. Our analysis suggests that Chinese emissions occur predominantly from the aluminum industry, although their emissions per production ratio may be improving. Our results for Japan and Korea find significant discrepancies between top-down and bottom-up emissions estimates, suggesting that the effectiveness of emission reduction systems (abatement) used in their semiconductor industries may be overestimated. Overall, our top-down results for East Asia contribute significantly to reducing the gap in the global PFC emission budgets.

2021

Distinct pathways associated with chromosomal aberration frequency in a cohort exposed to genotoxic compounds compared to general population

Niazi, Yasmeen; Thomsen, Hauke; Smolkova, Bozena; Vodickova, Ludmila; Vodenkova, Sona; Kroupa, Michal; Vymetalkova, Veronika; Kazimirova, Alena; Barancokova, Magdalena; Volkovova, Katarina; Staruchova, Marta; Hoffmann, Per; Nöthen, Markus M.; Dusinska, Maria; Musak, Ludovit; Vodička, Pavel; Hemminki, Kari; Försti, Asta

2019

Energetic particle precipitation influences global secondary ozone distribution

Jia, Jia; Murberg, Lise Eder; Løvset, Tiril; Orsolini, Yvan; Espy, Patrick Joseph; Zeller, Lilou C. G.; Salinas, Cornelius Csar Jude H.; Lee, Jae N.; Wu, Dong; Zhang, Jiarong

The secondary ozone layer is a global peak in ozone abundance in the upper mesosphere-lower thermosphere (UMLT) around 90-95 km. The effect of energetic particle precipitation (EPP) from geomagnetic processes on this UMLT ozone remains largely unexplored. In this research we investigated how the secondary ozone responds to EPP using satellite observations. In addition, the residual Mean Meridional Circulation (MMC) derived from model simulations and the atomic oxygen [O], atomic hydrogen [H], temperature measurements from satellite observations were used to characterise the residual circulation changes during EPP events. We report regions of secondary ozone enhancement or deficit across low, mid and high latitudes as a result of global circulation and transport changes induced by EPP. The results are supported by a sensitivity test using an empirical model.

2024

Estimating tropospheric and stratospheric winds using infrasound from explosions

Blixt, Erik Mårten; Näsholm, Sven Peter; Gibbons, Steven John; Evers, Laslo; Charlton-Perez, Andrew; Orsolini, Yvan; Kværna, Tormod

The receiver-to-source backazimuth of atmospheric infrasound signals is biased when cross-winds are present along the propagation path. Infrasound from 598 surface explosions from over 30 years in northern Finland is measured with high spatial resolution on an array 178 km almost due North. The array is situated in the classical shadow-zone distance from the explosions. However, strong infrasound is almost always observed, which is most plausibly due to partial reflections from stratospheric altitudes. The most probable propagation paths are subject to both tropospheric and stratospheric cross-winds, and the wave-propagation modelling in this study yields good correspondence between the observed backazimuth deviation and cross-winds from the European Centre for Medium-Range Weather Forecasts Reanalysis (ERA)-Interim reanalysis product. This study demonstrates that atmospheric cross-winds can be estimated directly from infrasound data using propagation time and backazimuth deviation observations. This study finds these cross-wind estimates to be in good agreement with the ERA-Interim reanalysis.

2019

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