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Vitenskapelig tidsskriftspublikasjon

Determining the Bio‐Based Carbon Content of Surfactants

Mudge, Stephen Michael; Tropsch, Juergen; Beaudouin, Thierry; Séné, Christophe; Hormazabal, Horacio


Tidsskrift: Journal of Surfactants and Detergents (JSD), vol. 23, 771–780, 2020

Arkiv: hdl.handle.net/11250/2654892
Doi: doi.org/10.1002/jsde.12411

In response to a mandate from the European Commission, the European Committee for Standardization (CEN) called on the technical committee CEN/TC 276 to develop a European standard (EN 17035) to define bio‐based surfactants and enable quantification of the bio‐based carbon content of surfactants based on radiocarbon analyses. This analytical approach was tested through directly contracted analyses and through a round robin procedure at commercial facilities in Europe. Initial results were unsatisfactory and further investigation identified issues surrounding the degree of homogenization in the samples. In general, the samples were only homogeneous at the gram level while the maximum quantity of material that could be introduced to the analytical process was at the milligram level. Having identified the root cause of the discrepancies between measured and expected results, new samples were sent to six European laboratories. The results were satisfactory indicating linearity and accuracy across the measurement range.