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Spatial Source Contribution and Interannual Variation in Deposition of Dust Aerosols Over the Chinese Loess Plateau

Haugvaldstad, Ove Westermoen; Tang, Hui; Kaakinen, Anu; Bohm, Katja; Zwaaftink, Christine Groot; Grythe, Henrik; Stevens, Thomas; Zhang, Zhongshi; Stordal, Frode

The Chinese Loess Plateau (CLP) in northern China is home to one of the most prominent loess records in the world, reflecting past eolian dust activity in East Asia. However, their interpretation is hampered by ambiguity in the origin of loess-forming dust and an incomplete understanding of the circulation forcing dust accumulation. In this study, we used a novel modeling approach combining a dust emission model FLEXDUST with simulated back trajectories from FLEXPART to trace the dust back to where it was emitted. Over 21 years (1999–2019), we modeled back trajectories for fine (∼2 μm) and super-coarse (∼20 μm) dust particles at six CLP sites during the peak dust storm season from March to May. FLEXPART source-receptor relationships are combined with the dust emission inventory from FLEXDUST to create site-dependent high-resolution maps of the source contribution of deposited dust. The nearby dust emission areas were found to be the main source of dust to the CLP. Dust deposition across the CLP was found to predominantly occur via wet removal, with also some super-coarse dust from distant emission regions being wet deposited following high-level tropospheric transport. The high topography located on the downwind side of the emission area plays an essential role in forcing the emitted super-coarse dust upward. On an interannual scale, the phase of the Arctic Oscillation in the preceding winter was found to have a strong association with the spring deposition rate on the CLP, while the strength of the East Asian Winter Monsoon was less influential.

American Geophysical Union (AGU)

2024

Spatial trends of chlorinated paraffins and dechloranes in air and soil in a tropical urban, suburban, and rural environment

Nipen, Maja; Vogt, Rolf David; Bohlin-Nizzetto, Pernilla; Borgå, Katrine; Mwakalapa, Eliezer Brown; Borgen, Anders; Jørgensen, Susanne Jøntvedt; Ntapanta, Samwel Moses; Mmochi, Aviti John; Schlabach, Martin; Breivik, Knut

There are large knowledge gaps concerning environmental levels and fate of many organic pollutants, particularly for chemicals of emerging concern in tropical regions of the Global South. In this study, we investigated the levels of chlorinated paraffins (CPs) and dechloranes in air and soil in rural, suburban, and urban regions in and around Dar es Salaam, Tanzania. Samples were also collected near the city's main municipal waste dumpsite and an electronic waste (e-waste) handling facility. In passive air samples, short chain CPs (SCCPs) dominated, with an average estimated concentration of 22 ng/m3, while medium chain CPs (MCCPs) had an average estimated concentration of 9 ng/m3. The average estimated air concentration of ∑dechloranes (Dechlorane Plus (DP) + Dechlorane 602 + Dechlorane 603) was three to four orders of magnitudes lower, 2 pg/m3. In soil samples, MCCPs dominated with an average concentration of 640 ng/g dw, followed by SCCPs with an average concentration of 330 ng/g dw, and ∑dechloranes with an average concentration of 0.9 ng/g dw. In both air and soil, DP was the dominating dechlorane compound. Urban pulses were observed for CPs and dechloranes in air and soil. CPs were in addition found in elevated levels at the municipal waste dumpsite and the e-waste handling facility, while DPs were found in elevated levels at the e-waste handling facility. This suggests that waste handling sites represent important emission sources for these pollutants. Investigations into seasonal trends and environmental fate of CPs and dechloranes showed that monsoonal rain patterns play a major role in governing air concentrations and mobility, particularly for the less volatile MCCPs and dechloranes. This study is the first to report levels of CPs in air from sub-Saharan Africa, and DP, Dechlorane 602, and Dechlorane 603 in soil from sub-Saharan Africa.

Springer

2021

Spatial trends of chlorinated paraffins and dechloranes in soil and air from Tanzania

Nipen, Maja; Bohlin-Nizzetto, Pernilla; Borgen, Anders; Borgå, Katrine; Jørgensen, Susanne Jøntvedt; Mmochi, Aviti John; Mwakalapa, Eliezer Brown; Schlabach, Martin; Vogt, Rolf David; Breivik, Knut

2020

Spatial variability and temporal changes of POPs in European background air

Halvorsen, Helene Lunder; Bohlin-Nizzetto, Pernilla; Eckhardt, Sabine; Gusev, Alexey; Möckel, Claudia; Shatalov, Victor; Skogeng, Lovise Pedersen; Breivik, Knut

Concentration data on POPs in air is necessary to assess the effectiveness of international regulations aiming to reduce the emissions of persistent organic pollutants (POPs) into the environment. POPs in European background air are continuously monitored using active- and passive air sampling techniques at a limited number of atmospheric monitoring stations. As a result of the low spatial resolution of such continuous monitoring, there is limited understanding of the main sources controlling the atmospheric burdens of POPs across Europe. The key objectives of this study were to measure the spatial and temporal variability of concentrations of POPs in background air with a high spatial resolution (n = 101) across 33 countries within Europe, and to use observations and models in concert to assess if the measured concentrations are mainly governed by secondary emissions or continuing primary emissions. Hexachlorobenzene (HCB) was not only the POP detected in highest concentrations (median: 67 pg/m3), but also the only POP that had significantly increased over the last decade. HCB was also the only POP that was positively correlated to latitude. For the other targeted POPs, the highest concentrations were observed in the southern part of Europe, and a declining temporal trend was observed. Spatial differences in temporal changes were observed. For example, γ-HCH (hexachlorocyclohexane) had the largest decrease in the south of Europe, while α-HCH had declined the most in central-east Europe. High occurrence of degradation products of the organochlorine pesticides and isomeric ratios indicated past usage. Model predictions of PCB-153 (2,2’,4,4’,5,5’-hexachlorobiphenyl) by the Global EMEP Multi-media Modelling System suggest that secondary emissions are more important than primary emissions in controlling atmospheric burdens, and that the relative importance of primary emissions are more influential in southern Europe compared to northern Europe. Our study highlights the major advantages of combining high spatial resolution observations with mechanistic modelling approaches to provide insights on the relative importance of primary- and secondary emission sources in Europe. Such knowledge is considered vital for policy makers aiming to assess the potential for further emission reduction strategies of legacy POPs.

Elsevier

2023

Spatial variability of flame retardants in indoor dust.

Jílkova, S.; Melymuk, L.; Vojta, S.; Bohlin-Nizzetto, P.; Kratka, M.; Klanova, J.

2015

Spatial Variability of POPs in Air at European Background Sites

Halvorsen, Helene Lunder; Bohlin-Nizzetto, Pernilla; Breivik, Knut; Eckhardt, Sabine; Moeckel, Claudia; Gusev, Alexey; Shatalov, Victor; Skogeng, Lovise Pedersen

2022

Spatial variability of POPs in European background air.

Halse, A. K.; Schlabach, M.; Eckhardt, S.; Sweetman, A.; Jones, K. C.; Breivik, K.

2011

Spatially valid data of atmospheric deposition of heavy metals and nitrogen derived by moss surveys for pollution risk assessments of ecosystems.

Schröder, W.; Nickel, S.; Schönrock, S.; Meyer, M.; Wosniok, W.; Harmens, H.; Frontasyeva, M. V.; Alber, R.; Aleksiayenak, J.; Barandovski, L.; Carballeira, A.; Danielsson, H.; de Temmermann, L.; Godzik, B.; Jeran, Z.; Karlsson, G. P.; Lazo, P.; Leblond, S.; Lindroos, A.-J.; Liiv, S.; Magnússon, S. H.; Mankovska, B.; Martínez-Abaigar, J.; Piispanen, J.; Poikolainen, J.; Popescu, I. V.; Qarri, F.; Santamaria, J. M.; Skudnik, M.; Špiric, Z.; Stafilov, T.; Steinnes, E.; Stihi, C.; Thöni, L.; Uggerud, H. T.; Zechmeister, H. G.

2016

Spatio-temporal variability of the polar middle atmosphere. Insights from over 30 years of research satellite observations. NILU TR

Lahoz, W.A.; Orsolini, Y.J.; Manney, G.L.; Minschwaner, K.; Allen, D.R.; Errera, Q.; Jackson, D.R.; Lambert, A.; Lee, J.; Pumphrey, H.; Schwartz, M.; Wu, D.

2012

Spatiotemporal Analysis of Perfluoroalkyl Substances in White-Tailed Eagle (Haliaeetus albicilla) Nestlings from Northern Norway-A Ten-Year Study

Jouanneau, William; Bårdsen, Bård-Jørgen; Herzke, Dorte; Johnsen, Trond Vidar; Eulaers, Igor; Bustnes, Jan Ove

The white-tailed eagle (Haliaeetus albicilla) in Scandinavia has suffered from impaired reproduction due to high exposure to industrial pollution between the 1960s and 1980s. While population numbers are rising again, new contaminants, such as per- and polyfluoroalkyl substances (PFAS), are increasingly found in high trophic avifauna and are of concern to potentially impact once again on population health. In the present study, we examined PFAS levels in plasma of white-tailed eagle nestlings from northern Norway over the last decade (2008–2017). While PFOA and PFNA exposure did not follow a significant time trend, PFOS and PFHxS concentrations decreased over time, and ≥C11 perfluorinated carboxylic acids only seem to level off during the last four years. This may in fact be the first evidence for a change in the trend for some of these compounds. Furthermore, since several PFAS are expected to be highly present in aqueous film-forming foams used at airports, we also investigate the potential of the two main airports in the region to act as hotspots for PFAS. Our results indeed show decreasing exposure to PFOA with distance to the airports. Altogether, our results seem to show that legislation actions are effective, and continued concern for PFAS exposure of high trophic wildlife is still warranted, even in the northern environment.

2020

Spatiotemporal Patterns in Data Availability of the Sentinel-5P NO2 Product over Urban Areas in Norway

Schneider, Philipp; Hamer, Paul David; Kylling, Arve; Shetty, Shobitha; Stebel, Kerstin

Due to its comparatively high spatial resolution and its daily repeat frequency, the tropospheric nitrogen dioxide product provided by the TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor platform has attracted significant attention for its potential for urban-scale monitoring of air quality. However, the exploitation of such data in, for example, operational assimilation of local-scale dispersion models is often complicated by substantial data gaps due to cloud cover or other retrieval limitations. These challenges are particularly prominent in high-latitude regions where significant cloud cover and high solar zenith angles are often prevalent. Using the example of Norway as a representative case for a high-latitude region, we here evaluate the spatiotemporal patterns in the availability of valid data from the operational TROPOMI tropospheric nitrogen dioxide (NO2) product over five urban areas (Oslo, Bergen, Trondheim, Stavanger, and Kristiansand) and a 2.5 year period from July 2018 through November 2020. Our results indicate that even for relatively clean environments such as small Norwegian cities, distinct spatial patterns of tropospheric NO2 are visible in long-term average datasets from TROPOMI. However, the availability of valid data on a daily level is limited by both cloud cover and solar zenith angle (during the winter months), causing the fraction of valid retrievals in each study site to vary from 20% to 50% on average. A temporal analysis shows that for our study sites and the selected period, the fraction of valid pixels in each domain shows a clear seasonal cycle reaching a maximum of 50% to 75% in the summer months and 0% to 20% in winter. The seasonal cycle in data availability shows the inverse behavior of NO2 pollution in Norway, which typically has its peak in the winter months. However, outside of the mid-winter period we find the TROPOMI NO2 product to provide sufficient data availability for detailed mapping and monitoring of NO2 pollution in the major urban areas in Norway and see potential for the use of the data in local-scale data assimilation and emission inversions applications.

MDPI

2021

Spatiotemporal patterns of indoor and outdoor PM2.5 in Legionowo, Poland

Salamalikis, Vasileios; Hassani, Amirhossein; Schneider, Philipp

2023

Spécification des Modèles d'Importation. NILU OR

Laupsa, H.; Bruno, M.

2008

Spesifikasjoner for sensorsystemer til måling av luftkvalitet. Anbefalinger ved anskaffelse.

Dauge, Franck Rene; Marsteen, Leif; Schneider, Philipp

Denne rapporten forklarer tekniske begrep knyttet til måleytelse, samt gir anbefalinger og krav i forbindelse med utarbeidelse av anbud. Rapporten går gjennom eksisterende instrumentering til luftkvalitetsmåling i Norge og gjeldende lovgivning rundt temaet. Den nevner mulige applikasjoner for ny sensorteknologi. En oversikt over metrologiske begrep sammen med forklaringer gir leseren grunnleggende kunnskap for å kunne tolke instrumentspesifikasjoner. Rapporten identifiserer noen viktige parametere knyttet til kvaliteten på sensorsystemer.

NILU

2018

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