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Homologue group profiles of ΣPCAs C14-17 in environmental samples from Norwegian monitoring programmes

Nipen, Maja; Borgen, Anders

Recently, chlorinated paraffins with carbon chain lengths in the range C14–17 and chlorination levels at or exceeding 45 per cent chlorine by weight have been proposed for listing under the Stockholm Convention. To aid the process of determining the identification of sum polychlorinated alkanes ΣPCAs C14-17 under the regulation (i.e. number of chlorines), there is a need for data from environmental samples that specifies the homologue group profiles, not just ΣPCAs.

In this report we present data on PCAs with a focus on ΣPCAs C14-17 from the Norwegian Environment Agency’s monitoring programmes in more detail than available in the programmes reports, focusing on homologue group patterns and chlorination degree. The programmes are i) Environmental pollutants in the terrestrial and urban environment ii) Atmospheric contaminants iii) Environmental contaminants in an urban fjord. Data presented are from the 2022 (Halvorsen et al., 2023; Heimstad et al., 2023; Ruus, 2023) and 2023 (reports in prep) programmes.

NILU

2024

Holocene black carbon in New Zealand lake sediment records

Brugger, Sandra O.; McWethy, David B.; Chellman, Nathan J.; Prebble, Matiu; Courtney Mustaphi, Colin J.; Eckhardt, Sabine; Plach, Andreas; Stohl, Andreas; Wilmshurst, Janet M.; McConnell, Joseph R.; Whitlock, Cathy

Elsevier

2024

Holistic methods for chemical screening and priority setting. NILU F

Arnot, J.A.; Brown, T.; Wania, F.; Breivik, K.; McLachlan, M.S.

2013

Ho Chi Minh City Environmental Improvement Project. Air Quality Monitoring Component. Mission 5, November 2004; Status report (QR10-11), Understanding air quality and data dissemination. NILU OR

Sivertsen, B.; Thanh, T.N.

Mission 5, as part of the NORAD financed IIEIA project, was undertaken to HCMC from 4 November to 4 December 2OO4. The air quality monitoring and management system has now been established and is being operated by trained TIEPA/DONRE experts. During Mission 5 we signed an agreement for the establishment of a Reference Laboratory and continued institutional building. NILU upgraded the AirQUIS system and we continued training the local experts. Data quality controls of air quality and meteorological data have been performed, and we continued collecting emission data for modelling purposes. During the mission we also prepared a paper on air quality in HCMC, which also will serve as a state of the environment report.

2005

Hitting the hotspots – Targeted deployment of air source heat pump technology to deliver clean air communities and climate progress: A case study of Ireland

Ó Broin, Eion; Kelly, J. Andrew; Sousa Santos, Gabriela; Grythe, Henrik; Svendby, Tove Marit; Solberg, Sverre; Kelleher, Luke; Clinch, J. Peter

Electrification of residential heating and investment in building energy efficiency are central pillars of many national strategies to reduce carbon emissions from the built environment sector. Ireland has a strong dependence on oil use for central heating and a substantial share of homes still using solid fuels. The current national strategy calls for the retrofitting of 400,000 home heating systems with heat pumps by 2030, principally replacing oil fired heating systems. Displacing natural gas, oil and solid fuel boilers with heat pumps will have a favourable impact on climate outcomes. However, the impact on air pollutant outcomes is far more favourable when solid fuels are replaced, and the positive impact on ambient air quality is much enhanced where concentrated clusters of solid-fuel use are targeted. This research spatially analyses emissions and air pollutant concentration outcomes for both targeted and non-targeted deployments of heat pumps and shows that a focused deployment of just 3% of the national heat pump target on solid-fuel homes could offer similar progress on climate goals but with a substantial impact in terms of reducing air pollution hot spots. For the Irish residential heating season (October–March), the targeted solid fuel scenario delivers average PM2.5 concentration decreases of 20–34%. This paper shows that these targeted communities are often in areas of relative deprivation, and as such, direct support for fabric retrofitting and heat pump technology installation offers the potential to simultaneously advance climate, air and just transition policy ambitions.

Elsevier

2022

History of chemically and radiatively important atmospheric gases from the Advanced Global Atmospheric Gases Experiment (AGAGE)

Prinn, Ronald G.; Weiss, Ray F.; Arduini, Jgor; Arnold, Tim; DeWitt, H. Langley; Fraser, Paul J.; Ganesan, Anita L.; Gasore, Jimmy; Harth, Christina M.; Hermansen, Ove; Kim, Jooil; Krummel, Paul B.; Li, Shanlan; Loh, Zöe M.; Lunder, Chris Rene; Maione, Michela; Manning, Alistair J.; Miller, Ben R.; Mitrevski, Blagoj; Muhle, Jens; O'Doherty, Simon; Park, Sunyoung; Reimann, Stefan; Rigby, Matt; Saito, Takuya; Salameh, Peter K.; Schmidt, Roland; Simmonds, Peter G.; Steele, L. Paul; Vollmer, Martin K.; Wang, Ray H.; Yao, Bo; Yokouchi, Yoko; Young, Dickon; Zhou, Lingxi

We present the organization, instrumentation, datasets, data interpretation, modeling, and accomplishments of the multinational global atmospheric measurement program AGAGE (Advanced Global Atmospheric Gases Experiment). AGAGE is distinguished by its capability to measure globally, at high frequency, and at multiple sites all the important species in the Montreal Protocol and all the important non-carbon-dioxide (non-CO2) gases assessed by the Intergovernmental Panel on Climate Change (CO2 is also measured at several sites). The scientific objectives of AGAGE are important in furthering our understanding of global chemical and climatic phenomena. They are the following: (1) to accurately measure the temporal and spatial distributions of anthropogenic gases that contribute the majority of reactive halogen to the stratosphere and/or are strong infrared absorbers (chlorocarbons, chlorofluorocarbons – CFCs, bromocarbons, hydrochlorofluorocarbons – HCFCs, hydrofluorocarbons – HFCs and polyfluorinated compounds (perfluorocarbons – PFCs), nitrogen trifluoride – NF3, sulfuryl fluoride – SO2F2, and sulfur hexafluoride – SF6) and use these measurements to determine the global rates of their emission and/or destruction (i.e., lifetimes); (2) to accurately measure the global distributions and temporal behaviors and determine the sources and sinks of non-CO2 biogenic–anthropogenic gases important to climate change and/or ozone depletion (methane – CH4, nitrous oxide – N2O, carbon monoxide – CO, molecular hydrogen – H2, methyl chloride – CH3Cl, and methyl bromide – CH3Br); (3) to identify new long-lived greenhouse and ozone-depleting gases (e.g., SO2F2, NF3, heavy PFCs (C4F10, C5F12, C6F14, C7F16, and C8F18) and hydrofluoroolefins (HFOs; e.g., CH2 = CFCF3) have been identified in AGAGE), initiate the real-time monitoring of these new gases, and reconstruct their past histories from AGAGE, air archive, and firn air measurements; (4) to determine the average concentrations and trends of tropospheric hydroxyl radicals (OH) from the rates of destruction of atmospheric trichloroethane (CH3CCl3), HFCs, and HCFCs and estimates of their emissions; (5) to determine from atmospheric observations and estimates of their destruction rates the magnitudes and distributions by region of surface sources and sinks of all measured gases; (6) to provide accurate data on the global accumulation of many of these trace gases that are used to test the synoptic-, regional-, and global-scale circulations predicted by three-dimensional models; and (7) to provide global and regional measurements of methane, carbon monoxide, and molecular hydrogen and estimates of hydroxyl levels to test primary atmospheric oxidation pathways at midlatitudes and the tropics. Network Information and Data Repository: http://agage.mit.edu/data or http://cdiac.ess-dive.lbl.gov/ndps/alegage.html (https://doi.org/10.3334/CDIAC/atg.db1001).

2018

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