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Organic contaminants (polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), and chlorinated paraffins (CPs)) and heavy metals and metalloids (Ag, Cd, Co, Cr, Cu, Hg, Ni, Pb, Sb, Zn) were analysed in surface soil samples from the Agbogbloshie e-waste processing and dumping site in Accra (Ghana). In order to identify which of the pollutants are likely to be linked specifically to handling of e-waste, samples were also collected from the Kingtom general waste site in Freetown (Sierra Leone). The results were compared using principal component analyses (PCA). PBDE congeners found in technical octa-BDE mixtures, highly chlorinated PCBs and several heavy metals (Cu, Pb, Ni, Cd, Ag and Hg) showed elevated concentrations in the soils that are likely due to contamination by e-waste. PCAs associated those compounds with pyrogenic PAHs, suggesting that burning of e-waste, a common practice to isolate valuable metals, may cause this contamination. Moreover, other contamination pathways, especially incorporation of waste fragments into the soil, also appeared to play an important role in determining concentrations of some of the pollutants in the soil. Concentrations of several of these compounds were extremely high (especially PBDEs, heavy metals and SCCPs) and in some cases exceeded action guideline levels for soil. This indicates that exposure to these contaminants via the soil alone is potentially harmful to the recyclers and their families living on waste sites. Many organic contaminants and other exposure pathways such as inhalation are not yet included in such guidelines but may also be significant, given that deposition from the air following waste burning was identified as a major pollutant source.
Elsevier
2020
Soil uptake of VOCs exceeds production when VOCs are readily available
Volatile organic compounds (VOCs) are reactive gaseous compounds with significant impacts on air quality and the Earth's radiative balance. While natural ecosystems are known to be major sources of VOCs, primarily due to vegetation, soils, an important component of these ecosystems, have received relatively less attention as potential sources and sinks of VOCs. In this study, soil samples were collected from two temperate ecosystems: a beech forest and a heather heath, and then sieved, homogenized, and incubated under various controlled conditions such as different temperatures, oxic vs. anoxic conditions, and different ambient VOC levels. A dynamic flow-through system coupled to a proton transfer reaction-time of flight-mass spectrometry (PTR-ToF-MS) was used to measure production and/or uptake rates of selected VOCs, aiming to explore the processes and their controlling mechanisms. Our results showed that these soils were natural sources of a variety of VOCs, and the strength and profile of these emissions were influenced by soil properties (e.g. moisture, soil organic matter), oxic/anoxic conditions, and temperature. The soils also acted as sinks for most VOCs when VOC substrates at parts per billions levels (ranging between 0.18 and 68.65 ppb) were supplied to the headspace of the enclosed soils, and the size of the sink corresponded to the amount of VOCs available in the ambient air. Temperature-controlled incubations and glass bead simulations indicated that the uptake of VOCs by soils was likely driven by microbial metabolism, with a minor contribution from physical adsorption to soil particles. In conclusion, our study suggests that soil uptake of VOCs can mitigate the impact of other significant VOC sources in the near-surface environment and potentially regulate the net exchange of these trace gases in ecosystems.
Elsevier
2023
2002
Solar UV radiation measurements in Marambio, Antarctica, during years 2017–2019
In March 2017, measurements of downward global irradiance of ultraviolet (UV) radiation were started with a multichannel GUV-2511 radiometer in Marambio, Antarctica (64.23∘ S; 56.62∘ W), by the Finnish Meteorological Institute (FMI) in collaboration with the Servicio Meteorológico Nacional (SMN). These measurements were analysed and the results were compared to previous measurements performed at the same site with the radiometer of the Antarctic NILU-UV network during 2000–2008 and to data from five stations across Antarctica. In 2017/2018 the monthly-average erythemal daily doses from October to January were lower than those averaged over 2000–2008 with differences from 2.3 % to 25.5 %. In 2017/2018 the average daily erythemal dose from September to March was 1.88 kJ m−2, while in 2018/2019 it was 23 % larger (2.37 kJ m−2). Also at several other stations in Antarctica the UV radiation levels in 2017/2018 were below average. The maximum UV indices (UVI) in Marambio were 6.2 and 9.5 in 2017/2018 and 2018/2019, respectively, whereas during years 2000–2008 the maximum was 12. Cloud cover, the strength of the polar vortex and the stratospheric ozone depletion are the primary factors that influence the surface UV radiation levels in Marambio. The lower UV irradiance values in 2017/2018 are explained by the high ozone concentrations in November, February and for a large part of October. The role of cloud cover was clearly seen in December, and to a lesser extent in October and November, when cloud cover qualitatively explains changes which could not be ascribed to changes in total ozone column (TOC). In this study, the roles of aerosols and albedo are of minor influence because the variation of these factors in Marambio was small from one year to the other. The largest variations of UV irradiance occur during spring and early summer when noon solar zenith angle (SZA) is low and the stratospheric ozone concentration is at a minimum (the so-called ozone hole). In 2017/2018, coincident low total ozone column and low cloudiness near solar noon did not occur, and no extreme UV indices were measured.
2020
Solar irradiance has been universally acknowledged to be dominant by quasi-decadal variability, which has been adopted frequently to investigate its effect on climate decadal variability. As one major terrestrial energy source, solar-wind energy flux into Earth's magnetosphere (Ein) exhibits dramatic interannual variation, the effect of which on Earth's climate, however, has not drawn much attention. Based on the Ein estimated by 3D magnetohydrodynamic simulations, we demonstrate a novelty that the annual mean Ein can explain up to 25% total interannual variance of the northern-hemispheric temperature in the subsequent boreal winter. The concurrent anomalous atmospheric circulation resembles the positive phase of Arctic Oscillation/North Atlantic Oscillation. The warm anomalies in the tropic stratopause and tropopause induced by increased solar-wind–magnetosphere energy persist into the subsequent winter. Due to the dominant change in the polar vortex and mid-latitude westerly in boreal winter, a ‘top-down’ propagation of the stationary planetary wave emerges in the Northern Hemisphere and further influences the atmospheric circulation and climate.
Oxford University Press
2020
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