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Kinetics of POP sorption and plastic additive release to a variety of polymers under Arctic conditions

Herzke, Dorte; Sakaguchi-Söder, Kaori; Sempere, Richard; Fauvelle, Vincent; Booth, Andy

The PLASTOX project investigates the ingestion, food-web transfer, and ecotoxicological impact of microplastics (MPs), together with the persistent organic pollutants (POPs), metals and plastic additive chemicals associated with them, on key European marine species and ecosystems. PLASTOX combines field-based observations, laboratory tests and manipulative field experiments to study the ecological effects of MPs.

As part of a long-term field experiment conducted at marine locations across Europe (Mediterranean to Arctic), a range of different virgin polymer pellets, post-use polymers (LDPE, PP, PS and PET), as well as marine litter-derived microplastic particles, were deployed underwater for up to 12 months in the small boat harbour of Tromsø, Northern Norway. The deployment device consisted of an empty stainless steel SPMD canister, with the various plastic types placed in reusable, empty 'teabags' made of PP, placed separately in nylon netting. Sampling was conducted 1 week, 1 month, 3 months, 6 months and 12 months after deployment. Hydrophobic persistent organic pollutants such as PAHs, PCBs, DDTs, PBDEs and pesticides that had become associated with the plastic were measured and their adsorption kinetics in seawater under Arctic conditions established. Samples were extracted using ultrasound and non-polar solvents, followed by GPC and SPE clean up prior to chemical analysis and quantification by GC/MS/MS and GC/qMS. The release kinetics of common plastic additives, including phthalates, organophosphate esters, bisphenols and perfluorinated chemicals, were estimated from four types of post-industrial virgin pellets (LDPE, PS, PVC, PET) according to the same sampling protocol. Chemical analysis was performed using either GC/MS or LC-QTOF.

Results show that HCB and PCBs represented the dominant pollutant classes adsorbing to all of the different polymer types, but at concentrations that are more than 10-times lower than those previously reported. However, equilibrium between pollutants and the polymers was not reached during the deployment period, indicating that Arctic conditions may result in different sorption kinetics than observed in temperate regions.

2018

iNANOD liposomes. Cyto- and genotoxicity testing.

Rundén-Pran, Elise; Hudecova, Alexandra Misci; Mariussen, Espen; Dusinska, Maria

NILU

2018

NILU’s Environmental Management Report 2017

Braathen, Ole-Anders; Marsteen, Leif; Langholen, Trine; Andresen, Eva Beate; Fjeldstad, Heidi

One of NILU’s main goals is to study the impact of pollution and supply decision-makers with a sound scientific platform for choosing measures to reduce the negative impacts. Furthermore, it is very important for the institute to have control of the impact the institute’s own activities may have on the environment and to reduce negative impacts as far as possible.

NILU has for many years been working to improve the status of the environment and to reduce negative impacts. In order to take this one step further, it was decided that the institute should restructure the work according to a relevant environmental standard and to seek certification according to the same standard.

The chosen standard is ISO 14001:2004 (Environmental management systems—Requirements with guidance for use) and NILU achieved certification according to this standard in October 2010. This report summarizes the results of the system in 2017.

NILU

2018

North Hemisphere air quality transects to assess legacy and emerging semivolatile organic contaminants

Ratola, Nuno; Cincinelli, Alessandra; Pieri, Francesca; Montesinos, Sonia; Schuster, Jasmin K.; Katsoyiannis, Athanasios A.; Del Vento, Sabino; Graf, Carola; Moeckel, Claudia; Martellini, Tania; Breivik, Knut; Lacorte, Silvia; Jiménez-Guerrero, Pedro; Santos, Lucia; Alves, Arminda; Sweetman, Andrew J.; Jones, Kevin C.

2018

Coral Reef Socio-Ecological Systems Analysis & Restoration

Uribe-Castaneda, Natalia; Newton, Alice; Le Tissier, Martin

Restoration strategies for coral reefs are usually focused on the recovery of bio-physical characteristics. They seldom include an evaluation of the recovery of the socio-ecological and ecosystem services features of coral reef systems. This paper proposes a conceptual framework to address both the socio-ecological system features of coral reefs with the implementation of restoration activity for degraded coral reefs. Such a framework can lead to better societal outcomes from restoration activities while restoring bio-physical, social and ecosystem service features of such systems. We first developed a Socio Ecological System Analysis Framework, which combines the Ostrom Framework for analyzing socio-ecological systems and the Kittinger et al. human dimensions framework of coral reefs socio-ecological systems. We then constructed a Restoration of Coral Reef Framework, based on the most used and recent available coral reef restoration literature. These two frameworks were combined to present a Socio-Ecological Systems & Restoration Coral Reef Framework. These three frameworks can be used as a guide for managers, researchers and decision makers to analyze the needs of coral reef restoration in a way that addresses both socio-economic and ecological objectives to analyze, design, implement and monitor reef restoration programs.

MDPI

2018

Plasma concentrations of organohalogenated contaminants in white-tailed eagle nestlings – The role of age and diet

Løseth, Mari Engvig; Briels, Nathalie; Eulaers, Igor; Nygård, Torgeir; Malarvannan, Govindan; Poma, Giulia; Covaci, Adrian; Herzke, Dorte; Bustnes, Jan Ove; Lepoint, Gilles; Jenssen, Bjørn Munro; Jaspers, Veerle

Elsevier

2018

Make it dirty: Simulating physical and chemical changes in mock-ups for the cleaning of unvarnished oil paintings by E. Munch

Stoveland, Lena Porsmo; Ormsby, Bronwyn; Stols-Witlox, Maartje; Grøntoft, Terje; Caruso, Francesco

2018

Spesifikasjoner for sensorsystemer til måling av luftkvalitet. Anbefalinger ved anskaffelse.

Dauge, Franck Rene; Marsteen, Leif; Schneider, Philipp

This report explains technical terms related to measuring performances, as well as providing recommendations and requirements in connection with preparation of tenders. The report goes through existing instrumentation for air quality measurement in Norway and current legislation on the subject. It mentions possible applications for new measurement technologies. An overview of metrological terms with explanations gives the reader basic knowledge necessary to interpret instrument specifications. The report identifies some important parameters related to the quality of sensor systems.

NILU

2018

Air quality in Ny-Ålesund. Monitoring of local air quality 2016-2017.

Johnsrud, Mona; Hermansen, Ove; Tørnkvist, Kjersti

The concentrations of the measured components are generally low and below national limit values for the protection of human health and critical levels for the protection of vegetation.

Wind from northern sectors gave the highest average concentrations of nitrogen oxides and sulphur dioxide, which indicates the power station and the harbour as possible sources. The measurement results for CO2 show an annual variation with higher concentrations in the winter and lower in summer. Measured concentrations of CO were most likely caused by local snowmobile traffic.

NILU

2018

Indoor air pollution impact on cultural heritage in an urban and a rural location in Romania: the National military museum in Bucharest and the Tismana monastery in Gorj County.

Grøntoft, Terje; Marincas, Octaviana

Assessment was performed of the air quality related risk to the conservation of cultural heritage objects in one urban and one rural indoor location in Romania, with expected different air quality related conservation challenges: the National military museum in Bucharest and the Tismana monastery in Gorj County. The work was performed within and subsequent to the EU-Memori project by applying Memori methodology, Memori®-EWO (Early warning organic) dosimeters and passive pollution badge samplers for acetic and formic acids. The measurements in the National military museum were performed in three rooms with different exposure situations, and inside protective enclosures in the rooms. The rooms had organic and inorganic objects on exhibition and in store. The observed risks were associated with photo-oxidizing impact probably due to traffic pollutants entering from outdoor, and/or light exposure and temperature. The risks were found to be moderate, generally comparable to typical European purpose built museum locations. The highest risk was observed in a more open exhibition room in the main museum building. It was indicated that some observable change might happen to sensitive pigments and paper within 3 years, and to lead, copper and sensitive glass within 30 years in this location. Risk for observable change to sensitive pigments, paper, lead and sensitive glass within 30 years, was indicated in the other locations. The lowest risk was observed in a warehouse. A reduction in photo-oxidizing risk was measured in two of the enclosures, but a slightly higher acidic impact was measured in all the three enclosures, as compared to the respective rooms. In the Tismana monastery, a high level of acetic plus formic acid was observed in the air in the storerooms for icons and textiles, and books. Damage risk within 3 years was indicated for lead objects and sensitive glass, and within 30 years for iron and varnish (Laropal A81, resin mastic and dammar). As organic acid attack increases significantly at higher air humidity (> ~ 60%), this would be especially important to avoid. Risk for photo-oxidizing damage to paper and sensitive pigments within 30 years was indicated.

BioMed Central (BMC)

2018

Concentrations and radiative forcing of anthropogenic aerosols from 1750 to 2014 simulated with the Oslo CTM3 and CEDS emission inventory

Lund, Marianne Tronstad; Myhre, Gunnar; Haslerud, Amund Søvde; Skeie, Ragnhild Bieltvedt; Griesfeller, Jan; Platt, Stephen Matthew; Kumar, Rajesh; Myhre, Cathrine Lund; Schulz, Michael

We document the ability of the new-generation Oslo chemistry-transport model, Oslo CTM3, to accurately simulate present-day aerosol distributions. The model is then used with the new Community Emission Data System (CEDS) historical emission inventory to provide updated time series of anthropogenic aerosol concentrations and consequent direct radiative forcing (RFari) from 1750 to 2014.

Overall, Oslo CTM3 performs well compared with measurements of surface concentrations and remotely sensed aerosol optical depth. Concentrations are underestimated in Asia, but the higher emissions in CEDS than previous inventories result in improvements compared to observations. The treatment of black carbon (BC) scavenging in Oslo CTM3 gives better agreement with observed vertical BC profiles relative to the predecessor Oslo CTM2. However, Arctic wintertime BC concentrations remain underestimated, and a range of sensitivity tests indicate that better physical understanding of processes associated with atmospheric BC processing is required to simultaneously reproduce both the observed features. Uncertainties in model input data, resolution, and scavenging affect the distribution of all aerosols species, especially at high latitudes and altitudes. However, we find no evidence of consistently better model performance across all observables and regions in the sensitivity tests than in the baseline configuration.

Using CEDS, we estimate a net RFari in 2014 relative to 1750 of −0.17 W m−2, significantly weaker than the IPCC AR5 2011–1750 estimate. Differences are attributable to several factors, including stronger absorption by organic aerosol, updated parameterization of BC absorption, and reduced sulfate cooling. The trend towards a weaker RFari over recent years is more pronounced than in the IPCC AR5, illustrating the importance of capturing recent regional emission changes.

2018

A satellite-based estimate of combustion aerosol cloud microphysical effects over the Arctic Ocean

Zamora, Lauren M; Kahn, Ralph A.; Huebert, Klaus B; Stohl, Andreas; Eckhardt, Sabine

Climate predictions for the rapidly changing Arctic are highly uncertain, largely due to a poor understanding of the processes driving cloud properties. In particular, cloud fraction (CF) and cloud phase (CP) have major impacts on energy budgets, but are poorly represented in most models, often because of uncertainties in aerosol–cloud interactions. Here, we use over 10 million satellite observations coupled with aerosol transport model simulations to quantify large-scale microphysical effects of aerosols on CF and CP over the Arctic Ocean during polar night, when direct and semi-direct aerosol effects are minimal. Combustion aerosols over sea ice are associated with very large (∼ 10Wm−2) differences in longwave cloud radiative effects at the sea ice surface. However, co-varying meteorological changes on factors such as CF likely explain the majority of this signal. For example, combustion aerosols explain at most 40% of the CF differences between the full dataset and the clean-condition subset, compared to between 57% and 91% of the differences that can be predicted by co-varying meteorology. After normalizing for meteorological regime, aerosol microphysical effects have small but significant impacts on CF, CP, and precipitation frequency on an Arctic-wide scale. These effects indicate that dominant aerosol–cloud microphysical mechanisms are related to the relative fraction of liquid-containing clouds, with implications for a warming Arctic.

2018

Methane at Svalbard and over the European Arctic Ocean

Platt, Stephen Matthew; Eckhardt, Sabine; Ferré, Benedicte; Fisher, Rebecca E.; Hermansen, Ove; Jansson, Pär; Lowry, David; Nisbet, Euan G.; Pisso, Ignacio; Schmidbauer, Norbert; Silyakova, Anna; Stohl, Andreas; Svendby, Tove Marit; Vadakkepuliyambatta, Sunil; Mienert, Jurgen; Myhre, Cathrine Lund

2018

Curating scientific information in knowledge infrastructures

Stocker, Markus; Paasonen, Pauli; Fiebig, Markus; Zaidan, Martha A; Hardisty, Alex

Interpreting observational data is a fundamental task in the sciences, specifically in earth and environmental science where observational data are increasingly acquired, curated, and published systematically by environmental research infrastructures. Typically subject to substantial processing, observational data are used by research communities, their research groups and individual scientists, who interpret such primary data for their meaning in the context of research investigations. The result of interpretation is information—meaningful secondary or derived data—about the observed environment. Research infrastructures and research communities are thus essential to evolving uninterpreted observational data to information. In digital form, the classical bearer of information are the commonly known “(elaborated) data products,” for instance maps. In such form, meaning is generally implicit e.g., in map colour coding, and thus largely inaccessible to machines. The systematic acquisition, curation, possible publishing and further processing of information gained in observational data interpretation—as machine readable data and their machine readable meaning—is not common practice among environmental research infrastructures. For a use case in aerosol science, we elucidate these problems and present a Jupyter based prototype infrastructure that exploits a machine learning approach to interpretation and could support a research community in interpreting observational data and, more importantly, in curating and further using resulting information about a studied natural phenomenon.

Ubiquity Press

2018

Discussion on the representativeness of current methodologies to assess indoor air quality

Vogt, Matthias; Hak, Claudia; Lopez-Aparicio, Susana; Dauge, Franck Rene; Holøs, Sverre Bjørn; Mysen, Mads

2018

Effect of filter type in ventilation systems on NO2 concentrations in classrooms

Yang, Aileen; Nikolaisen, Kristian Fredrik; Holøs, Sverre Bjørn; Thunshelle, Kari; Dauge, Franck Rene; Mysen, Mads

2018

Discussion on the representativeness of current methodologies to assess indoor air quality

Vogt, Matthias; Hak, Claudia; Lopez-Aparicio, Susana; Dauge, Franck Rene; Holøs, Sverre Bjørn; Yang, Aileen; Mysen, Mads

2018

Assessing the Relocation Robustness of on Field Calibrations for Air Quality Monitoring Devices

Esposito, E; Salvato, M; De Vito, S.; Fattoruso, G; Castell, Nuria; Karatzas, K.; Francia, G Di

Springer

2018

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