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Hazard and exposure assessment of do-it-yourself products forimpregnation

Højriis, Sara; Christensen, Frans; Larssen, Carsten; Nikiforov, Vladimir; Sørli, Jorid Birkelund; Jensen, Alexander Christian Østerskov (eds.)

A large number of do-it-yourself impregnation products are marketed to Danish consumers. The products are typically used for re-impregnation of consumer products (e.g. footware and outdoor clothing) immediately after the products have been purchased or when the water and/or dirt-repellent effect begins to diminish.

The Danish Environmental Protection Agency has chosen to make a survey of the market, where 110 do-it-yourself impregnation products were identified within ten different application categories. Out of these products, 14 were included in initial chemical content analyzes, as well as hazard and exposure analyzes. The main components in the majority of the products were saturated hydrocarbons, but some of the products also contained oxygen-containing solvents (e.g. alcohols, ethers, esters or ketones). The potential hazard of 12 of the 14 selected impregnation spray products was performed by measuring acute respiratory toxicity. Of the 12 products tested, 10 inhibited the function of the lung surfactant and may therefore potentially be harmful by inhalation.

On the basis of this study, it could not be demonstrated that the products with PFAS resulted in an inhibition of the lung surfactant at lower doses as compared to products without PFAS; in fact, the lowest inhibitory doses were seen for impregnating agents based on siloxanes/silicones. The results show that the hazardous properties of an impregnation product cannot be determined solely on the basis of the ingredients, and it is therefore necessary to examine the ability of the individual products to inhibit the lung surfactant in connection with a hazard assessment.

Danish Environmental Protection Agency

2023

Forsvinner lukt? Eller blir planeten vår mer og mer illeluktende for hver dag som går?

Nikiforov, Vladimir (intervjuobjekt); Schou, Ingrid (journalist)

2023

Røykpartikler fra Canada har nådd Sørlandet

Tørseth, Kjetil; Evangeliou, Nikolaos (intervjuobjekter); Skår, Kari Løberg; Bjøranger, Ada Drevdal (journalister)

2023

Gigant-skogbranner kan ses fra verdensrommet – røykpartikler har nådd Norge

Evangeliou, Nikolaos (intervjuobjekt); Berger, Nina Dayana (journalist)

2023

Revidert tiltaksutredning for lokal luftkvalitet i Drammen

Weydahl, Torleif; Markelj, Miha; Høyem, Harald

NILU – Norsk institutt for luftforskning har, i samarbeid med Asplan Viak AS, utarbeidet en tiltaksutredning for lokal luftkvalitet i Drammen kommune. Tiltaksutredningen omfatter en kartlegging av luftkvaliteten i Drammen ved trafikkberegninger og utslipps- og spredningsberegninger for svevestøv (PM10 og PM2,5) for Dagens situasjon 2021 og Referansesituasjonen 2030 og for 2030 med tiltak rettet mot svevestøv. Basert på resultatene fra beregningene og i samarbeid med oppdragsgiver, styringsgruppe og referansegruppe, er det foreslått en revidert handlingsplan som skal behandles politisk.

NILU

2023

Mapping potential conflicts between global agriculture and terrestrial conservation

Hoang, Nguyen Tien; Taherzadeh, Oliver; Ohashi, Haruka; Yonekura, Yusuke; Nishijima, Shota; Yamabe, Masaki; Matsui, Testuya; Matsuda, Hiroyuki; Moran, Daniel Dean; Kanemoto, Keiichiro

Demand for food products, often from international trade, has brought agricultural land use into direct competition with biodiversity. Where these potential conflicts occur and which consumers are responsible is poorly understood. By combining conservation priority (CP) maps with agricultural trade data, we estimate current potential conservation risk hotspots driven by 197 countries across 48 agricultural products. Globally, a third of agricultural production occurs in sites of high CP (CP > 0.75, max = 1.0). While cattle, maize, rice, and soybean pose the greatest threat to very high-CP sites, other low-conservation risk products (e.g., sugar beet, pearl millet, and sunflower) currently are less likely to be grown in sites of agriculture–conservation conflict. Our analysis suggests that a commodity can cause dissimilar conservation threats in different production regions. Accordingly, some of the conservation risks posed by different countries depend on their demand and sourcing patterns of agricultural commodities. Our spatial analyses identify potential hotspots of competition between agriculture and high-conservation value sites (i.e., 0.5° resolution, or ~367 to 3,077km2, grid cells containing both agriculture and high-biodiversity priority habitat), thereby providing additional information that could help prioritize conservation activities and safeguard biodiversity in individual countries and globally. A web-based GIS tool at https://agriculture.spatialfootprint.com/biodiversity/ systematically visualizes the results of our analyses.

2023

Monitoring persistent organic chemicals in Antarctica in support of global chemical policy: a horizon scan of priority actions and challenges

Bengtson Nash, Susan; Bohlin-Nizzetto, Pernilla; Galban-Malagon, Cristobal; Corsolini, Simonetta; Cincinelli, Alessandra; Lohmann, Rainer

Global production and emission of chemicals exceeds societal capacities for assessment and monitoring. This situation calls for improved chemical regulatory policy frameworks and increased support for expedited decision making within existing frameworks. The polar regions of the Earth represent unique sentinel areas for the study of global chemical behaviour, and data arising from these areas can strengthen existing policy frameworks. However, chemical pollution research and monitoring in the Antarctic is underdeveloped, with geopolitical complexities and the absence of legal recognition of international chemical policy serving to neutralise progress made in other global regions. This Personal View represents a horizon scan by the action group Input Pathways of Persistent Organic Pollutants to Antarctica, of the Scientific Committee for Antarctic Research. Four priority research and research facilitation gaps are outlined, with recommendations for Antarctica Treaty parties for strategic action against these priorities.

Elsevier

2023

Halogen chemistry in volcanic plumes: a 1D framework based on MOCAGE 1D (version R1.18.1) preparing 3D global chemistry modelling

Marécal, Virginie; Voisin-Plessis, Ronan; Roberts, Tarda Jane; Aiuppa, Alessandro; Narivelo, Herizo; Hamer, Paul David; Josse, Beatrice; Guth, Jonathan; Surl, Luke

HBr emissions from volcanoes lead rapidly to the formation of BrO within volcanic plumes and have an impact on tropospheric chemistry, at least at the local and regional scales. The motivation of this paper is to prepare a framework for further 3D modelling of volcanic halogen emissions in order to determine their fate within the volcanic plume and then in the atmosphere at the regional and global scales. The main aim is to evaluate the ability of the model to produce a realistic partitioning of bromine species within a grid box size typical of MOCAGE (Model Of atmospheric Chemistry At larGE scale) 3D (0.5∘ × 0.5∘). This work is based on a 1D single-column configuration of the global chemistry-transport model MOCAGE that has low enough computational cost to allow us to perform a large set of sensitivity simulations. This paper uses the emissions from the Mount Etna eruption on 10 May 2008. Several reactions are added to MOCAGE to represent the volcanic plume halogen chemistry. A simple plume parameterisation is also implemented and tested. The use of this parameterisation tends to only slightly limit the efficiency of BrO net production. Both simulations with and without the parameterisation give results for the partitioning of the bromine species, of ozone depletion and of the ratio that are consistent with previous studies.

A series of test experiments were performed to evaluate the sensitivity of the results to the composition of the emissions (primary sulfate aerosols, Br radical and NO) and to the effective radius assumed for the volcanic sulfate aerosols. Simulations show that the plume chemistry is sensitive to all these parameters. We also find that the maximum altitude of the eruption changes the BrO production, which is linked to the vertical variability of the concentrations of oxidants in the background air. These sensitivity tests display changes in the bromine chemistry cycles that are generally at least as important as the plume parameterisation. Overall, the version of the MOCAGE chemistry developed for this study is suitable to produce the expected halogen chemistry in volcanic plumes during daytime and night-time.

2023

Exploring microplastic contamination in reef-associated fishes of the Tropical Atlantic

Justino, Anne K.S.; Ferreira, Guilherme V.B.; Fauvelle, Vincent; Schmidt, Natascha; Lenoble, Veronique; Pelage, Latifa; Lucena-Fredou, Flavia

Elsevier

2023

SensEURCity: A multi-city air quality dataset collected for 2020/2021 using open low-cost sensor systems

Van Poppel, Martine; Schneider, Philipp; Peters, Jan; Yatkin, Sinan; Gerboles, Michel; Matheeussen, Christina; Bartonova, Alena; Davila, Silvije; Signorini, Marco; Vogt, Matthias; Dauge, Franck Rene; Skaar, Jøran Solnes; Haugen, Rolf

Low-cost air quality sensor systems can be deployed at high density, making them a significant candidate of complementary tools for improved air quality assessment. However, they still suffer from poor or unknown data quality. In this paper, we report on a unique dataset including the raw sensor data of quality-controlled sensor networks along with co-located reference data sets. Sensor data are collected using the AirSensEUR sensor system, including sensors to monitor NO, NO2, O3, CO, PM2.5, PM10, PM1, CO2 and meteorological parameters. In total, 85 sensor systems were deployed throughout a year in three European cities (Antwerp, Oslo and Zagreb), resulting in a dataset comprising different meteorological and ambient conditions. The main data collection included two co-location campaigns in different seasons at an Air Quality Monitoring Station (AQMS) in each city and a deployment at various locations in each city (also including locations at other AQMSs). The dataset consists of data files with sensor and reference data, and metadata files with description of locations, deployment dates and description of sensors and reference instruments.

Springer Nature

2023

Implications of Regurgitative Feeding on Plastic Loads in Northern Fulmars (Fulmarus glacialis): A Study from Svalbard

Tulatz, Felix; Gabrielsen, Geir Wing; Bourgeon, Sophie; Herzke, Dorte; Krapp, Rupert; Langset, Magdalene; Neumann, Svenja; Lippold, Anna; Collard, France

Procellariiform seabirds like northern fulmars (Fulmarus glacialis) are prone to ingest and accumulate floating plastic pieces. In the North Sea region, there is a long tradition to use beached fulmars as biomonitors for marine plastic pollution. Monitoring data revealed consistently lower plastic burdens in adult fulmars compared to younger age classes. Those findings were hypothesized to partly result from parental transfer of plastic to chicks. However, no prior study has examined this mechanism in fulmars by comparing plastic burdens in fledglings and older fulmars shortly after the chick-rearing period. Therefore, we investigated plastic ingestion in 39 fulmars from Kongsfjorden (Svalbard), including 21 fledglings and 18 older fulmars (adults/older immatures). We found that fledglings (50−60 days old) had significantly more plastic than older fulmars. While plastic was found in all fledglings, two older fulmars contained no and several older individuals barely any plastic. These findings supported that fulmar chicks from Svalbard get fed high quantities of plastic by their parents. Adverse effects of plastic on fulmars were indicated by one fragment that perforated the stomach and possibly one thread perforating the intestine. Negative correlations between plastic mass and body fat in fledglings and older fulmars were not significant.

2023

Overview of plastic ingestion by fulmars in Svalbard over 25 years: what is next?

Collard, France; Benjaminsen, Stine Charlotte; Herzke, Dorte; Husabø, Eirin; Krapp, Rupert; Tulatz, Felix; Gabrielsen, Geir Wing

2023

50 Human Hazard Assessment of Nanomaterials: Supporting Risk Decision Making Through Interlaboratory Trial Data

Burgum, Michael J.; El Yamani, Naouale; Longhin, Eleonora Marta; Mariussen, Espen; Rundén-Pran, Elise; Sosnowska, Anita; Puzyn, Tomasz; Clift, Martin J. D.; Dusinska, Maria; Doak, Shareen H.

Oxford University Press

2023

Chlorinated paraffins in urban air in Nordic countries

Bohlin-Nizzetto, Pernilla; Borgen, Anders; Nipen, Maja

In 2022, the Joint Nordic screening group decided to perform a Nordic study on short-, medium- and long-chain chlorinated paraffins (SCCPs, MCCPs, LCCPs) in urban air. A previous study performed on behalf of screening group in 2019 observed higher concentrations of chlorinated paraffins (CPs) in air samples from an urban site than from remote sites (Schlabach et al. 2022). It was then suggested that tire wear particles could be the source for the elevated urban concentrations.

The focus of the study in 2022 was to collect data to improve the understanding of sources for CPs in air by: (1) comparing concentrations measured in wintertime when studded tires are used and in summertime when normal tires are used, (2) comparing data from three capitals in the Nordic countries, and (3) compare urban air concentrations to air concentrations in a car tire testing facility. All the member countries were invited to participate but based on the possibilities to collect active air samples in urban locations, it was decided to collect air samples from Helsinki (Finland), Reykjavik and Reykjanesbær (Iceland) and Oslo (Norway). Samples were collected in February–March 2022 and May–August 2022. The sampling time for each sample was 48 hrs and 3–6 samples were collected per site and season.

Nordic Council of Ministers

2023

Review of methods that can be used in the assessment of atmospheric deposition

Aas, Wenche; Soares, Joana; Hamer, Paul David; Schneider, Philipp; Svendby, Tove Marit; Guerreiro, Cristina

There are three main approaches for estimating the atmospheric deposition: 1) From measurements of air and precipitation chemistry combined with statistical interpolation, 2) Chemical transport models, 3) Combined observations and atmospheric model calculations. This report reviews these different approaches and come with some general recommendations on the different strategies and the way forward for Poland.

The report was made for the project "Strengthening of atmospheric deposition assessment in Poland based on Norwegian experience" under the program "Environment, Energy and Climate Change", financed by the European Economic Area Financial Mechanism 2014-2021".

NILU

2023

Antarctic sea-ice low resonates in the ecophysiology of humpback whales

Nash, Susan M. Bengtson; Groß, Jasmin; Castrillon, Juliana; Casa, Maria Valeria; Luche, Greta Dalle; Meager, Justin James; Ghosh, Ruma; Eggebo, June; Bohlin-Nizzetto, Pernilla

The past six years have been marked by some of the most dramatic climatic events observed in the Antarctic region in recent history, commencing with the 2017 sea-ice extreme low. The Humpback Whale Sentinel Programme is a circum-polar biomonitoring program for long term surveillance of the Antarctic sea-ice ecosystem. It has previously signalled the extreme La Niña event of 2010/11, and it was therefore of interest to assess the capacity of existing biomonitoring measures under the program to detect the impacts of 2017 anomalous climatic events. Six ecophysiological markers of population adiposity, diet, and fecundity were targeted, as well as calf and juvenile mortality via stranding records. All indicators, with the exception of bulk stable isotope dietary tracers, indicated a negative trend in 2017, whilst C and N bulk stable isotopes appeared to indicate a lag phase resulting from the anomalous year. The collation of multiple biochemical, chemical, and observational lines of evidence via a single biomonitoring platform provides comprehensive information for evidence-led policy in the Antarctic and Southern Ocean region.

Elsevier

2023

Feathers as Temporal Archives of Ecological Stress and Metal Exposure in a Terrestrial Raptor: A Long- Term Study on Breeding Tawny Owls

Hansen, Elisabeth; Bustnes, Jan Ove; Eulaers, Igor; Herzke, Dorte; Bårdsen, Bård-Jørgen; Bangjord, Georg; Bourgeon, Sophie; Ballesteros, Manuel

2023

Long-range atmospheric transport of currently-used pesticides over Europe

Mayer, Ludovic; Senk, Petr; Pribylova, Petra; Kukučka, Petr; Durand, Amadine; Ravier, Sylvain; Alastuey, Andres; Baker, Alex R.; Baltensperger, Urs; Baumann-Stanzer, Kathrin; Biermann, Tobias; Bohlin-Nizzetto, Pernilla; Ceburnis, Darius; Conil, Sébastien; Couret, Cedric; Degorska, Anna; Diapouli, Evangelia; Eckhardt, Sabine; Eleftheriadis, Konstantinos; Forster, Grant L.; Freier, Korbinian; Gheusi, Francois; Gini, Maria; Hellén, Heidi; Henne, Stephan; Herrmann, Hartmut; Horrak, Urmas; Smejkalova, Adeala Holubova; Hueglin, Christoph; Junninen, Heikki; Kristensson, Adam; Langrene, Laurent; Levula, Janne; Lien, Olav; Lothon, Marie; Ludewig, Elke; Lyngra, Reidar; Makkonen, Ulla; Markussen, Helge Tore; Matejovičová, Jana; Mihalopoulos, Nikos; Mináriková, Veronika; Moche, Wolfgang; Noe, Steffen M.; Pérez, Noemi; Petäjä, Tuukka; Pont, Veronique; Poulain, Laurent; Quivet, Etienne; Ratz, Gabriela; Rehm, Till; Reimann, Stefan; Simmons, Ivan; Sonke, Jeroen E.; Sorribas, Mar; Spoor, Ronald; Swart, Daan P.J.; Vassilatou, Vassiliki; Wortham, Henri; Yela, Margarita; Zarmpas, Pavlos; Zellweger, Claudia; Tørseth, Kjetil; Laj, Paolo G.; Klanova, Jana; Lammel, Gerhard; Degrendele, Celine

2023

Fluorine Mass-balance in Pooled Serum Samples from Northern Norwegian Men and Women Between 1986 and 2015

Cioni, Lara; Plassmann, Merle; Benskin, Jonathan; Coelho, Ana Carolina; Nøst, Therese Haugdahl; Rylander, Karin Charlotta Maria; Nikiforov, Vladimir; Herzke, Dorte; Sandanger, Torkjel M

2023

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