Fant 2611 publikasjoner. Viser side 19 av 262:
Brominated flame retardants (BFRs) that are gradually being phased out are being replaced by emerging BFRs. Here, we report the concentration of the α- and β-isomers of 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane (TBECH; also known as DBE-DBCH) in over 300 air, water, and precipitation samples collected between 2019 and 2022 using active air and deposition sampling as well as networks of passive air and water samplers. The sampling region includes Canada's most populated cities and areas along the St. Lawrence River and Estuary, Quebec, as well as around the Salish Sea, British Columbia. TBECH was detected in over 60 % of air samples at levels comparable to those of 2,2′,4,4′-tetrabromodiphenyl ether (BDE-47). Concentrations of TBECH and BDE-47 were typically higher in urban areas, with stronger correlations with population density during warmer deployments. Uniform α- β-TBECH ratios across space, time, and environmental media indicate the highly similar atmospheric fate of the two isomers. Although TBECH air concentrations were strongly related to temperature in urban Toronto and a remote site on the east coast, the lack of such dependence at a remote site on the west coast can be explained by the small seasonal temperature range and summertime air mass transport from the Pacific Ocean. Despite there being no evidence that TBECH has been produced, or imported for use, in Canada, it is now one of the most abundant gaseous BFRs in the Canadian atmosphere. The recorded spatial and temporal variability of TBECH suggest that its emissions are not constrained to specific locations but are generally tied to the presence of humans. The most likely explanation for its environmental occurrence in Canada is the release from imported consumer products containing TBECH. Chiral analysis suggests that despite its urban origin, at least some fraction of TBECH has experienced enantioselective processing, i.e., has volatilized from reservoirs where it has undergone microbial transformations. Microbial processes in urban soils and in marine waters may have divergent enantioselectivity.
2023
Cross-modal representation learning aims to learn a shared representation space where data from multiple modalities can be effectively compared, fused, and understood. This paper investigates the role of increased diversity in the similarity score matrix in enhancing the performance of the CLIP (Contrastive Language-Image Pretraining), a multi-modal learning model that establishes a connection between images and text within a joint embedding space. Two transforming approaches, sine and sigmoid (including two versions), are incorporated into the CLIP model to amplify larger values and diminish smaller values within the similarity matrix (logits). Hardware limitations are addressed using a more compact text encoder (DistilBERT) and a pre-trained ResNet50 image encoder. The proposed adaptations are evaluated on various benchmarks, including image classification and image/text retrieval tasks, using 10 benchmark datasets such as Food101, Flickr30k, and COCO. The performance of the adapted models is compared to the base CLIP model using Accuracy, mean per class, and Recall@k metrics. The results demonstrate improvements in Accuracy (up to 5.32% enhancement for the PatchCamelyon dataset), mean per class (up to 14.48% enhancement for the FGVCAircraft dataset), and retrieval precision (with an increase of up to 45.20% in Recall@1 for the COCO dataset), compared to the baseline algorithm (CLIP).
IEEE (Institute of Electrical and Electronics Engineers)
2023
As wild-caught fish become scarce, feed ingredients for farming fish, such as salmon, are increasingly sourced from agricultural plants that depend on mineral fertilizers. Since these fish are naturally carnivorous, they have difficulty digesting the phosphorus in plant-based feed. So additional phosphorus supplements are added to the feed, resulting in a disproportionate increase in mineral phosphorus use and emission. Aquatic food production is increasingly relying on agriculture and mineral phosphorus resources. The feed surplus and the excreta are seldom collected and recycled, leading to a massive loss of nutrients to water bodies and the seafloor, resulting in local risk for eutrophication. Norway currently produces more than half of the world’s Atlantic salmon, and it is set to increase production from currently 1.5 to 5 Mt. in 2050. This has large implications for feed supply and emissions globally. There is a lack of studies that analyze the phosphorus system in aquatic food production at a sufficient spatial and temporal granularity to effectively inform interventions for a more circular use of phosphorus. Here, we present a multi-scale phosphorus flow analysis at monthly resolution ranging between 2005 and 2021 for aquatic food production in Norway and quantitatively discuss the effectiveness of alternative strategies for improving resource efficiency. The results indicate that P emissions from aquaculture have nearly doubled in the period between 2005 and 2021. The P use efficiency (PUE) in Norwegian aquaculture was 19% in 2021. The addition of phytase to the feed could improve the PUE by 8% by reducing P supplements and emissions by 7 kt/y. The use of Integrated Multi-Trophic Aquaculture close to fish farming sites could absorb emissions by 4 kt/y by creating new marine food products. Sludge collection systems could reduce P emissions by 4 to 11 kt/y, depending on the technology. Using the sludge in local agriculture would exacerbate the current P accumulation in soils close to the coastline, given that the animal density in this region is already high. Hence, a large and sophisticated processing infrastructure will be needed to create transportable, high-quality secondary fertilizers for effective sludge recycling in regions with a P deficit.
Frontiers Media S.A.
2023
Review of Interpreting Gaseous Pollution Data Regarding Heritage Objects
Pollutant gases pose a significant risk to some cultural heritage objects, and surveys have shown that the professionals involved consider themselves to lack knowledge to fully assess risk. Three approaches towards risk assessment, research results, standards and damage functions have been considered. An assessment tool has been developed, collating over 4000 research reports into a scheme for the impact on 22 materials of acetic and formic acids, nitrogen dioxide, ozone and reduced sulphur gases. The application of doses or concentrations has been considered, the impact of measurement time compared to annual exposure investigated and a simple tool derived.
MDPI
2023
A rise in HFC-23 emissions from eastern Asia since 2015
Trifluoromethane (CHF3, HFC-23), one of the most potent greenhouse gases among hydrofluorocarbons (HFCs), is mainly emitted to the atmosphere as a by-product in the production of the ozone-depleting legacy refrigerant and chemical feedstock chlorodifluoromethane (CHClF2, HCFC-22). A recent study on atmospheric observation-based global HFC-23 emissions (top-down estimates) showed significant discrepancies over 2014–2017 between the increase in the observation-derived emissions and the 87 % emission reduction expected from capture and destruction processes of HFC-23 at HCFC-22 production facilities implemented by national phase-out plans (bottom-up emission estimates) (Stanley et al., 2020). However, the actual regions responsible for the increased emissions were not identified. Here, we estimate the regional top-down emissions of HFC-23 for eastern Asia based on in situ measurements at Gosan, South Korea, and show that the HFC-23 emissions from eastern China have increased from 5.0±0.4 Gg yr−1 in 2008 to 9.5±1.0 Gg yr−1 in 2019. The continuous rise since 2015 was contrary to the large emissions reduction reported under the Chinese hydrochlorofluorocarbons production phase-out management plan (HPPMP). The cumulative difference between top-down and bottom-up estimates for 2015–2019 in eastern China was Gg, which accounts for 47±11 % of the global mismatch. Our analysis based on HCFC-22 production information suggests the HFC-23 emissions rise in eastern China is more likely associated with known HCFC-22 production facilities rather than the existence of unreported, unknown HCFC-22 production, and thus observed discrepancies between top-down and bottom-up emissions could be attributed to unsuccessful factory-level HFC-23 abatement and inaccurate quantification of emission reductions.
2023
An increasing number of organisms from the polar regions are reported contaminated by plastic. Rarely a non-killing sampling method is used. In this study we wanted to assess plastic levels using stomach flushing and evaluate the method suitability for further research and monitoring. The stomach of 22 fulmars from Bjørnøya, Svalbard, were flushed with water in the field. On return to the laboratory, the regurgitated content was digested using potassium hydroxide. The extracted plastics were visually characterised and analysed with spectroscopy. Only three birds had plastics in their stomach, totaling 36 particles, most of them microplastics (< 5 mm). The plastic burdens are much lower than previously reported in Svalbard. The stomach flushing is assumed not to allow the collection of the gizzard content. This is a major limitation as most of the plastics accumulate in the fulmar's gizzard. However, the method is still useful for studies investigating plastic ingestion dynamics, allowing to sample the same individuals over time.
Elsevier
2023
Poland continues to rely heavily on coal and fossil fuels for household heating, despite efforts to reduce Particulate Matter (PM) levels. The availability of reliable air quality data is essential for policymakers, environmentalists, and citizens to advocate for cleaner energy sources. However, Polish air quality monitoring is challenging due to the limited coverage of reference stations and outdated equipment. Here, we report the results of a study on the spatio-temporal variability of Particulate Matter in Legionowo, Poland, using residents’ network of low-cost sensors. Along with identifying the hotspots of household-emitted PM, (1) we propose a data quality assurance scheme for PM sensors, (2) suggest an approach for estimating the Relative Humidity-induced uncertainty in the sensors without co-location with reference instruments, and (3) develop an interpretable Machine Learning (ML) model, a Generalized Additive Model (RMSE = 6.16 μg m−3, and R2 = 0.88), for unveiling the underlying relations between PM2.5 levels and other environmental parameters. The results in Legionowo suggest that as air temperature and wind speed increase by 1 °C and 1 km h−1, PM2.5 would respectively decrease by 0.26 μg m−3 and 0.14 μg m−3 while PM2.5 increases by 0.03 μg m−3 as RH increases by 1%.
Elsevier
2023
Car tire rubber constitutes one of the largest fractions of microplastics emissions to the environment. The two main emission sources are tire wear particles (TWPs) formed through abrasion during driving and runoff of crumb rubber (CR) granulate produced from end-of-life tires that is used as infill on artificial sports fields. Both tire wear particles and crumb rubber contain a complex mixture of metal and organic chemical additives, and exposure to both the particulate forms and their leachates can cause adverse effects in aquatic species. An understanding of the exposure pathways and mechanisms of toxicity are, however, scarce. While the most abundant metals and organic chemicals in car tire rubber have multiple other applications, para-phenylenediamines (PDs) are primarily used as rubber antioxidants and were recently shown to cause negative effects in aquatic organisms. The present study investigated the responses of the marine lumpfish (Cyclopterus lumpus) to crumb rubber exposure in a controlled feeding experiment. Juvenile fish were offered crumb rubber particles with their feed for 1 week, followed by 2 weeks of depuration. Crumb rubber particle ingestion occurred in >75% of exposed individuals, with a maximum of 84 particles observed in one specimen. Gastrointestinal tract retention times varied, with some organisms having no crumb rubber particles and others still containing up to 33 crumb rubber particles at the end of the experiment. Blood samples were analyzed for metals and organic chemicals, with ICP-MS analysis revealing there was no uptake of metals by the exposed fish. Interestingly, high resolution GC-MS analysis indicated that uptake of PDs into lumpfish blood was proportionate to the number of ingested CR particles. Three of the PDs found in blood were the same as those identified in the additive mixture Vulkanox3100. N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine (6PPD) was the most concentrated PD in both the crumb rubber and lumpfish blood. The transformation product 6PPD-quinone was detected in the rubber material, but not in the blood. This study demonstrates that PDs are specific and bioavailable chemicals in car tire rubber that have the potential to serve as biomarkers of recent exposure to tire chemicals, where simple blood samples could be used to assess recent tire chemical exposure in vertebrates, including humans.
Frontiers Media S.A.
2023
This paper examines the potential impact of citizen science on achieving SDGs in cities. The analysis focuses on projects funded through the European Research Framework Programmes that utilize citizen science practices to involve cities and citizens in addressing sustainability issues. We analyzed a total of 44 projects active between 2016 and 2027, encompassing both ongoing and completed projects. Instead of relying solely on existing literature, we utilized a project database called CORDIS to gather project information. This approach allowed us to develop a comprehensive framework by utilizing uniformly classified data from the database, which is not typically available in literature. Using a four-stage framework analysis method, we assessed the projects' thematic areas, goals, types of solution promoted or tested to address sustainability challenges, methodologies employed, and the impacts achieved or expected. Through this analysis, we identified successful collaborations between citizen science and cities, showcasing examples of effective practice where citizens and cities co-created and tested solutions that contribute to SDGs. This highlights the active role that citizens, as participants or citizen scientists, play in the transition toward SDGs. This study focuses on more than 100 European cities that have been involved in EU-funded research projects implementing and planning to conduct citizen science activities, which directly and indirectly link to various SDGs. Our findings reveal that citizen science practices in cities predominantly address SDG3 (Good health and wellbeing), 11 (Sustainable cities and communities), and 13 (Climate action). Cities that engage citizens in co-creating solutions can enhance their capacity to improve quality of life and reduce climate and environmental impacts. Citizen engagement at the city and community levels can bolster efforts toward achieving SDGs and monitoring progress on a city-wide scale. However, to fully integrate citizen science and its contribution to cities in achieving SDGs, further research is needed to align the SDGs formulated at the national level with those at the city level. This entails exploring how citizen science can align with SDGs indicators and the quantification of SDG targets. Such efforts will facilitate the mainstreaming of citizen science and its potential to drive progress toward SDGs in cities.
Frontiers Media S.A.
2023
The Sub-Millimetre Radiometer (SMR) on board the Odin satellite provides almost 20 years of nitric oxide (NO) measurements in the mesosphere and lower thermosphere (MLT) at equatorial crossing local solar times (LSTs) of 6 AM and 6 PM. In this study, we use Odin/SMR observations to estimate how lower thermospheric NO mixing ratios at low latitudes are affected by solar nonmigrating tides. Most of the previous studies based on satellite data have focused on the signatures of diurnal tides in the MLT and above, while we concentrate here on nonmigrating semidiurnal tides. To study the contribution of these tides to NO mixing ratio variations, we average pairs of NO measurements along ascending and descending orbital tracks at 107 km altitude over latitudes between −40°and +40°. We consider monthly climatologies of these pair-averages and analyse residuals with respect to their zonal mean. In this way, it is possible to study the effect of nonmigrating even-numbered tidal components, albeit there is a non-tidal component arising largely from quasi-stationary planetary waves. Spectral wave amplitudes are extracted using a Fourier transform as function of (apparent) zonal wavenumber with a focus around −30°, −20°and 30°latitudes. From our analysis, it appears that the semidiurnal (apparent) zonal wavenumber 4 arising from the SW6 and SE2 tides is dominant close to the equator (e.g., at −20°), except during some boreal summer months (June, July, August). On the other hand, wave-1 plays a more prominent role at subtropical latitudes, especially in the southern hemisphere, where it surpasses wave-4 during 7 months (March and May-to-October) at −30°. There is little observational evidence to date documenting the presence of the semidiurnal nonmigrating tides in NO in the low-latitude MLT. Our results hence provide one of the first evidences of the climatological signature of these tides in NO, in an altitude range that remains poorly observed.
Elsevier
2023